The union of photoredox and nickel catalysis has resulted in a renaissance in radical
chemistry as well as in the use of nickel‐catalyzed transformations, specifically for carbon …

The concept of using amide bond distortion to modulate amidic resonance has been known
for more than 75 years. Two classic twisted amides (bridged lactams) ingeniously designed …

Reductive cross‐electrophile coupling reactions have recently been developed to a versatile
and sustainable synthetic tool for selective C C bond formation. The employment of cheap …

The scarcity of precious metals has led to the development of sustainable strategies for
metal‐catalyzed cross‐coupling reactions. The establishment of new catalytic methods …

Reported here is the redox neutral electrochemical C (sp2)− C (sp3) cross‐coupling reaction
of bench‐stable aryl halides or β‐bromostyrene (electrophiles) and benzylic trifluoroborates …

The combination of catalytic methods provides multiple advantages in organic synthesis,
allowing access to diverse organic molecules in a straightforward manner. Merging metal …

A large number of immobilized‐Pd‐catalysts for cross‐coupling reactions have been
introduced in the last decade. Are the observed catalyzed reactions truly heterogeneous or …

Palladium‐catalyzed coupling reactions have become a powerful tool for advanced organic
synthesis. This type of reaction is of significant value for the preparation of pharmaceuticals …

When reacted in the presence of external oxidants, gold complexes are capable of
catalyzing oxidative homo‐and cross‐coupling reactions involving the formation of new C …

In the past decade, transition-metal-catalyzed arene CÀH bond functionalization reactions
have enjoyed tremendous advances owing to their widespread applications to the rapid …