Controversy on the toxic nature of deep eutectic solvents and their potential contribution to environmental pollution

GM Martínez, GG Townley, RM Martínez-Espinosa - Heliyon, 2022 - cell.com
Deep eutectic solvents (DES) are promising reaction media where interesting catalytic
processes can be carried out. In theory, most of these mixtures are environmentally friendly …

Magnetically supported ionic liquids: a sustainable catalytic route for organic transformations

R Gupta, M Yadav, R Gaur, G Arora, P Yadav… - Materials …, 2020 - pubs.rsc.org
From solvents to catalytic applications, ionic liquids have received burgeoning interest ever
since their discovery. They belong to a class of salt-like materials that have unusually low …

[HTML][HTML] COSMO-RS prediction and experimental verification of 1, 5-pentanediamine extraction from aqueous solution by ionic liquids

C Jiang, H Cheng, Z Qin, R Wang, L Chen… - Green Energy & …, 2021 - Elsevier
Pentanediamine (PDA) produced by biological fermentation becomes popular, but the
separation of PDA from the broth is a typical difficult problem. In this work, the performance …

1, 3‐Dipolar Cycloaddition Reactions of Nitrile Oxides under “Non‐Conventional” Conditions: Green Solvents, Irradiation, and Continuous Flow

J Plumet - ChemPlusChem, 2020 - Wiley Online Library
Abstract The 1, 3‐dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes
and alkynes are useful methods for the synthesis of 2‐isoxazolines and isoxazoles …

Effect of 1-ethyl-3-methylimidazolium tetrafluoroborate and acetate ionic liquids on stability and amyloid aggregation of lysozyme

D Fedunova, A Antosova, J Marek, V Vanik… - International Journal of …, 2022 - mdpi.com
Amyloid fibrils draw attention as potential novel biomaterials due to their high stability,
strength, elasticity or resistance against degradation. Therefore, the controlled and fast …

Enzymatic synthesis of carbohydrates and glycoconjugates using lipases and glycosidases in green solvents

C García, P Hoyos, MJ Hernáiz - Biocatalysis and …, 2018 - Taylor & Francis
The wide use of carbohydrate-based compounds is the pharmaceutical, cosmetic, detergent
and food industry has led to the development of efficient synthetic procedures to overcome …

Water at the ionic liquid–gas interface examined by ambient pressure X-ray photoelectron spectroscopy

A Broderick, Y Khalifa, MB Shiflett… - The Journal of Physical …, 2017 - ACS Publications
Ambient pressure X-ray photoelectron spectroscopy (APXPS) was used to quantitatively
assess the chemical changes of the top few nanometers of the ionic liquid (IL)–gas interface …

Antibiofilm activity of tert-BuOH functionalized ionic liquids with methylsulfonate counteranions

GR Navale, MS Dharne, SS Shinde - RSC advances, 2015 - pubs.rsc.org
A series of varying alkyl chain length substituted tert-BuOH-functionalized-imidazolium
mesylate salts [alkyl-tOHim][OMs] were synthesized and evaluated for antimicrobial activity …

Recent innovations of organo-fluorine synthesis and pharmacokinetics

O Kamble, R Dandela, S Shinde - Current Organic Chemistry, 2021 - benthamdirect.com
The fluorinated compounds have significance in medicinal chemistry and pharmaceutical
research. The introduction of fluorine atom in the heterocyclic compounds increases …

Biomass-derived solvents

M Miele, L Ielo, V Pillari, M Fernández, A Alcántara… - 2021 - books.rsc.org
A well-k nown paradigm inside Green Chemistry states that “the best solvent is no solvent”.
1, 2 Nevertheless, most of the known organic transformations do require the use of solvents …