Progress on germanium–tin nanoscale alloys

J Doherty, S Biswas, E Galluccio… - Chemistry of …, 2020 - ACS Publications
Group IV alloys have attracted interest in the drive to create Si compatible, direct band gap
materials for implementation in complementary metal oxide semiconductor (CMOS) and …

Ge 1− x Sn x alloy quantum dots with composition-tunable energy gaps and near-infrared photoluminescence

V Tallapally, TA Nakagawara, DO Demchenko… - Nanoscale, 2018 - pubs.rsc.org
Low-cost, less-toxic, and abundantly-produced Ge1− xSnx alloys are an interesting class of
narrow energy-gap semiconductors that received noteworthy interest in optical technologies …

Epitaxial Ge0.81Sn0.19 Nanowires for Nanoscale Mid-Infrared Emitters

MS Seifner, A Dijkstra, J Bernardi, A Steiger-Thirsfeld… - ACS …, 2019 - ACS Publications
Highly oriented Ge0. 81Sn0. 19 nanowires have been synthesized by a low-temperature
chemical vapor deposition growth technique. The nanostructures form by a self-seeded …

Metastable group IV allotropes and solid solutions: Nanoparticles and nanowires

S Barth, MS Seifner, S Maldonado - Chemistry of Materials, 2020 - ACS Publications
In the past decades, group IV nanowires and nanoparticles have been the subject of
extensive research. Beside tremendous progress in morphological control and integration in …

One-Step fabrication of GeSn branched nanowires

J Doherty, S Biswas, D McNulty, C Downing… - Chemistry of …, 2019 - ACS Publications
We report for the first time the self-catalyzed, single-step growth of branched GeSn
nanostructures by a vapor–liquid–solid mechanism. These typical GeSn nanostructures …

Strain engineering in Ge/GeSn core/shell nanowires

S Assali, M Albani, R Bergamaschini… - Applied Physics …, 2019 - pubs.aip.org
Strain engineering in Sn-rich group IV semiconductors is a key enabling factor to exploit the
direct bandgap at mid-infrared wavelengths. Here, we investigate the effect of strain on the …

Kinetic control of morphology and composition in Ge/GeSn core/shell nanowires

S Assali, R Bergamaschini, E Scalise, MA Verheijen… - ACS …, 2020 - ACS Publications
The growth of Sn-rich group-IV semiconductors at the nanoscale can enrich the
understanding of the fundamental properties of metastable GeSn alloys. Here, we …

Direct synthesis of hyperdoped germanium nanowires

MS Seifner, M Sistani, F Porrati, G Di Prima, P Pertl… - ACS …, 2018 - ACS Publications
A low-temperature chemical vapor growth of Ge nanowires using Ga as seed material is
demonstrated. The structural and chemical analysis reveals the homogeneous incorporation …

[HTML][HTML] In situ TEM heating experiments on thin epitaxial GeSn layers: Modes of phase separation

K Martínez, A Minenkov, J Aberl, D Buca, M Brehm… - APL Materials, 2023 - pubs.aip.org
The thermal stability of GeSn epitaxial thin films was investigated via in situ transmission
electron microscopy (TEM). Samples were grown with a similar layer structure and 10 at …

Improved Surface Passivation of Colloidal Ge1–xSnx Nanoalloys through Amorphous SiO2 Shell Growth

DZ Spera, IU Arachchige - The Journal of Physical Chemistry C, 2022 - ACS Publications
Ge1–x Sn x alloy nanocrystals (NCs) are a class of semiconductors that show interesting
(photo) physical properties such as composition-dependent visible to near-IR energy gaps …