Stimuli-responsive metal–ligand assemblies

AJ McConnell, CS Wood, PP Neelakandan… - Chemical …, 2015 - ACS Publications
Within living systems, molecular-scale responses to stimuli flow together into the intricate
and robust signal transduction networks that process information for an organism. Studies of …

Supramolecular transformations within discrete coordination-driven supramolecular architectures

W Wang, YX Wang, HB Yang - Chemical Society Reviews, 2016 - pubs.rsc.org
In this review, a comprehensive summary of supramolecular transformations within discrete
coordination-driven supramolecular architectures, including helices, metallacycles …

Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Bent anthracene dimers as versatile building blocks for supramolecular capsules

M Yoshizawa, L Catti - Accounts of chemical research, 2019 - ACS Publications
Conspectus This Account provides a comprehensive summary of our 1-decade-long
investigations into bent anthracene dimers as versatile building blocks for supramolecular …

Geometric Complementarity in Assembly and Guest Recognition of a Bent Heteroleptic cis-[Pd2LA2LB2] Coordination Cage

WM Bloch, Y Abe, JJ Holstein… - Journal of the …, 2016 - ACS Publications
Due to the inherent difficulties in achieving a defined and exclusive formation of
multicomponent assemblies against entropic predisposition, we present the rational …

Identification of a Heteroleptic Pd6L6L′6 Coordination Cage by Screening of a Virtual Combinatorial Library

S Sudan, RJ Li, SM Jansze, A Platzek… - Journal of the …, 2021 - ACS Publications
The design of structurally defined heteroleptic coordination cages is a challenging task, and
only few examples are known to date. Here we describe a selection approach that allowed …

Pseudo‐heterolepticity in Low‐Symmetry Metal‐Organic Cages

JEM Lewis - Angewandte Chemie, 2022 - Wiley Online Library
Heteroleptic metal‐organic cages, formed through integrative self‐assembly of ligand
mixtures, are highly attractive as reduced symmetry supramolecular hosts. Ensuring high …

Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes

CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Controlled self-assembly and multistimuli-responsive interconversions of three conjoined twin-cages

LX Cai, DN Yan, PM Cheng, JJ Xuan… - Journal of the …, 2021 - ACS Publications
Stimuli-responsive structural transformations between discrete coordination supramolecular
architectures not only are essential to construct smart functional materials but also provide a …

Heterotrimetallic double cavity cages: syntheses and selective guest binding

LS Lisboa, D Preston, CJ McAdam… - Angewandte Chemie …, 2022 - Wiley Online Library
A strategy for the generation of heterotrimetallic double cavity (DC) cages [PdnPtmL4]
6+(DC1: n= 1, m= 2; and DC2: n= 2, m= 1) is reported. The DC cages were generated by …