Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N-Donor Ligands
PJ Panak, A Geist - Chemical reviews, 2013 - ACS Publications
The transuranium elements (TRU) neptunium, plutonium, americium, and curium are
produced in nuclear fuel during reactor operation from neutron capture by uranium-235/238 …
produced in nuclear fuel during reactor operation from neutron capture by uranium-235/238 …
Structure and thermodynamics of lanthanide and actinide complexes in solution
GR Choppin - Pure and Applied Chemistry XIIIth, 1971 - degruyter.com
Several questions of importance in the study of lanthanide and actinide coordination
compounds are reviewed. There is considerable evidence that in aqueous solution the …
compounds are reviewed. There is considerable evidence that in aqueous solution the …
Next-Generation 3, 3′-AlkoxyBTPs as Complexants for Minor Actinide Separation from Lanthanides: A Comprehensive Separations, Spectroscopic, and DFT Study
LS Fletcher, ML Tedder, SO Olayiwola… - Inorganic …, 2024 - ACS Publications
Progress toward the closure of the nuclear fuel cycle can be achieved if satisfactory
separation strategies for the chemoselective speciation of the trivalent actinides from the …
separation strategies for the chemoselective speciation of the trivalent actinides from the …
Advancing the Am Extractant Design through the Interplay among Planarity, Preorganization, and Substitution Effects
Advancing the field of chemical separations is important for nearly every area of science and
technology. Some of the most challenging separations are associated with the americium …
technology. Some of the most challenging separations are associated with the americium …
2,6-Bis(5-(2,2-dimethylpropyl)-1H-pyrazol-3-yl)pyridine as a Ligand for Efficient Actinide(III)/Lanthanide(III) Separation
A Bremer, CM Ruff, D Girnt, U Müllich… - Inorganic …, 2012 - ACS Publications
The N-donor complexing ligand 2, 6-bis (5-(2, 2-dimethylpropyl)-1 H-pyrazol-3-yl) pyridine
(C5-BPP) was synthesized and screened as an extracting agent selective for trivalent …
(C5-BPP) was synthesized and screened as an extracting agent selective for trivalent …
Comparative Investigation into the Complexation and Extraction Properties of Tridentate and Tetradentate Phosphine Oxide‐Functionalized 1, 10‐Phenanthroline …
L Xu, Y Hao, X Yang, Z Wang, C Xu… - … A European Journal, 2021 - Wiley Online Library
Two new phosphine oxide‐functionalized 1, 10‐phenanthroline ligands, tetradentate 2, 9‐
bis (butylphenylphosphine oxide)‐1, 10‐phenanthroline (BuPh‐BPPhen, L1) and tridentate …
bis (butylphenylphosphine oxide)‐1, 10‐phenanthroline (BuPh‐BPPhen, L1) and tridentate …
Complexation of Cm (III) and Eu (III) with a hydrophilic 2, 6-bis (1, 2, 4-triazin-3-yl)-pyridine studied by time-resolved laser fluorescence spectroscopy
CM Ruff, U Müllich, A Geist, PJ Panak - Dalton Transactions, 2012 - pubs.rsc.org
The complexation of Cm (III) and Eu (III) with 2, 6-bis (5, 6-di (sulfophenyl)-1, 2, 4-triazin-3-yl)
pyridine (aq-BTP) is studied in water at pH 3.0 applying time-resolved laser fluorescence …
pyridine (aq-BTP) is studied in water at pH 3.0 applying time-resolved laser fluorescence …
Computing UV/vis spectra using a combined molecular dynamics and quantum chemistry approach: bis-triazin-pyridine (BTP) ligands studied in solution
S Höfener, M Trumm, C Koke, J Heuser… - Physical Chemistry …, 2016 - pubs.rsc.org
We report a combined computational and experimental study to investigate the UV/vis
spectra of 2, 6-bis (5, 6-dialkyl-1, 2, 4-triazin-3-yl) pyridine (BTP) ligands in solution. In order …
spectra of 2, 6-bis (5, 6-dialkyl-1, 2, 4-triazin-3-yl) pyridine (BTP) ligands in solution. In order …
A hydrolytically stable complexant for minor An separation from Ln in process relevant diluents
LS Fletcher, ML Tedder, SO Olayiwola… - Chemical …, 2024 - pubs.rsc.org
The evaluation of bis-1, 2, 4-triazine complexants containing eight-carbon, alkoxy-
functionalized phenyl substituents at the 3, 3′-positions for selective minor actinide …
functionalized phenyl substituents at the 3, 3′-positions for selective minor actinide …
Gas-Phase Complexes of Americium and Lanthanides with a Bis-Triazinyl Pyridine: Reactivity and Bonding of Archetypes for F-Element Separations
Bis-triazinyl pyridines (BTPs) exhibit solution selectivity for trivalent americium over
lanthanides (Ln), the origins of which remain uncertain. Here, electrospray ionization was …
lanthanides (Ln), the origins of which remain uncertain. Here, electrospray ionization was …