Suzuki–Miyaura (SM) cross-coupling is arguably the most widely-applied transition metal
catalysed carbon–carbon bond forming reaction to date. Its success originates from a …

Research related to boronic acids, from synthetic development to materials to drug
discovery, has skyrocketed in the past 20 years. In terms of drug discovery, the incorporation …

A significant fraction of patients with advanced prostate cancer treated with androgen
deprivation therapy experience relapse with relentless progression to lethal metastatic …

Abstract The Suzuki–Miyaura coupling is one of the few transition‐metal‐catalyzed C C
bond‐forming reactions that have been used in applications ranging from discovery …

Organotrifluoroborates represent an alternative to boronic acids, boronate esters, and
organoboranes for use in Suzuki− Miyaura and other transition-metal-catalyzed cross …

Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most
straightforward and powerful ways to introduce aryl fragments in an enantioselective …

Organometallic reagents (RM) are of increasing importance not only for organometallic
chemists but also in organic chemistry and pharmaceutical synthesis and to access organic …

Abstract In Suzuki–Miyaura reactions, anionic bases F− and OH−(used as is or generated
from CO32− in water) play multiple antagonistic roles. Two are positive: 1) formation of trans …

We report the meta halogenation of 1, 3-disubstituted arenes to form 3, 5-disubstituted aryl
bromides and chlorides by using iridium-catalyzed arene borylation chemistry. Iridium …

Structurally, boronic acids are trivalent boron-containing organic compounds that possess
one alkyl substituent (ie, a C–B bond) and two hydroxyl groups to fill the remaining valences …