Multimetallic catalysis based on heterometallic complexes and clusters

P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

Direct amide synthesis from alcohols and amines by phosphine‐free ruthenium catalyst systems

SC Ghosh, S Muthaiah, Y Zhang, X Xu… - Advanced Synthesis & …, 2009 - Wiley Online Library
Amides are synthesized directly from alcohols and amines in high yields using an in situ
generated catalyst from easily available ruthenium complexes such as the (p‐cymene) …

Direct amide synthesis from either alcohols or aldehydes with amines: activity of Ru (II) hydride and Ru (0) complexes

S Muthaiah, SC Ghosh, JE Jee, C Chen… - The Journal of …, 2010 - ACS Publications
An in situ generated catalyst from readily available RuH2 (PPh3) 4, an N-heterocyclic
carbene (NHC) precursor, NaH, and acetonitrile was developed. The catalyst showed high …

Iron/copper co-catalyzed synthesis of vinyl sulfones from sulfonyl hydrazides and alkyne derivatives

G Rong, J Mao, H Yan, Y Zheng… - The Journal of Organic …, 2015 - ACS Publications
A new approach to the selective synthesis of (E)-vinyl sulfones has been developed via a
Fe/Cu co-catalyzed sulfonylation of arylpropiolic acid or phenylacetylene with sulfonyl …

Hydrocarbamoylation of unsaturated bonds by nickel/Lewis-acid catalysis

Y Nakao, H Idei, KS Kanyiva… - Journal of the American …, 2009 - ACS Publications
Formamides are found to undergo addition reactions across alkynes and 1, 3-dienes by
nickel/Lewis acid catalysis to give a variety of α, β-and β, γ-unsaturated amides with stereo …

Ruthenium-and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z, E)-dienamides

J Zhang, TP Loh - Chemical Communications, 2012 - pubs.rsc.org
Ruthenium-and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides
with alkenes were developed. These methods provide an efficient route for the synthesis of …

Iron-catalyzed hydroaminocarbonylation of alkynes: selective and efficient synthesis of primary α, β-unsaturated amides

Z Huang, J Tang, X Jiang, T Xie, M Zhang, D Lan… - Chinese Chemical …, 2022 - Elsevier
Abstract α, β-Unsaturated primary amides are important intermediates and building blocks in
organic synthesis. Herein, we report a ligand-free iron-catalyzed hydroaminocarbonylation …

Palladium‐Catalyzed Alkyne Hydrocyanation toward Ligand‐Controlled Stereodivergent Synthesis of (E)‐ and (Z)‐Trisubstituted Acrylonitriles

J Long, R Zhao, GJ Cheng… - Angewandte Chemie …, 2023 - Wiley Online Library
We herein describe a palladium‐catalyzed hydrocyanation of propiolamides for the
stereodivergent synthesis of trisubstituted acrylonitriles. This synthetic method tolerated …

Palladium-catalyzed carbonylative synthesis of α, β-unsaturated amides from styrenes and nitroarenes

JB Peng, HQ Geng, D Li, X Qi, J Ying, XF Wu - Organic letters, 2018 - ACS Publications
A procedure on palladium-catalyzed selective aminocarbonylation of styrenes with
nitroarenes for the synthesis of α, β-unsaturated amides has been developed. A range of …

Alkyl bromides as mild hydride sources in Ni-catalyzed hydroamidation of alkynes with isocyanates

X Wang, M Nakajima, E Serrano… - Journal of the American …, 2016 - ACS Publications
Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with
Isocyanates | Journal of the American Chemical Society ACS ACS Publications C&EN CAS …