Transition‐metal‐catalyzed copolymerization of olefins with polar monomers represents a
challenge because of the large variety of substrate‐induced side reactions. However, this …

Transition metal-catalyzed olefin-polar monomer copolymerization holds great potential for
the synthesis of polar group-functionalized polyolefin materials. The dominant approach to …

Polyethylenes enjoy wide applications due to their many superior properties. The
incorporation of some polar functional groups into the otherwise nonpolar polyethylene …

Self-healing materials are of fundamental interest and practical importance. Herein we
report the synthesis of a new class of self-healing materials, formed by the copolymerization …

Introducing polar functional groups into widely used polyolefins can enhance polymer
surface, rheological, mixing, and other properties, potentially upgrading polyolefins for …

The unexpected phenomenon and mechanism of the alkali metal involved NH3 selective
catalysis are reported. Incorporation of K+ (4.22 wt%) in the tunnels of α‐MnO2 greatly …

Ethylene/polar monomer coordination copolymerization offers an attractive way of making
functionalized polyolefins. However, ethylene copolymerization with industrially relevant …

The most straightforward and potentially ideal route to produce polar-functionalized
polyethylene is direct copolymerization of ethylene with polar monomers. However, access …

The terpolymerization of a non‐polar olefin (such as ethylene) and two different polar
functional olefins in a controlled fashion is of great interest and importance but has hardly …

Alternating copolymers have the clearest and most defined microstructures among
manmade polymers, having been promising building blocks to access synthetic polymers …