Exploiting the versatility of palladium catalysis: A modern toolbox for cascade reactions

S Mondal, T Ballav, K Biswas, S Ghosh… - European Journal of …, 2021 - Wiley Online Library
Palladium‐catalyzed cascade cyclization received much attention in organic synthesis due
to its efficiency and rapid transformation of simple starting materials into complex molecular …

Rapid Assembly of Functionalized 2H-Chromenes and 1,2-Dihydroquinolines via Microwave-Assisted Secondary Amine-Catalyzed Cascade Annulation of 2-O/N …

D Rajput, G Jan, M Karuppasamy… - The Journal of …, 2023 - ACS Publications
An efficient, secondary amine-catalyzed cascade annulation of 2-O/N-
propargylarylaldehydes with 2, 6-dialkylphenols was established to access biologically …

Enantioselective synthesis of fused isocoumarins via palladium-catalyzed annulation of alkyne-tethered malononitriles

H Zhang, W Li, XD Hu, WB Liu - The Journal of Organic Chemistry, 2021 - ACS Publications
An enantioselective palladium-catalyzed annulation of alkyne-tethered malononitriles for the
synthesis of 3, 4-ring-fused isocoumarins is described. This cascade strategy involves …

Revealing the Role of Solvent in anti-Oxypalladation-Triggered Regiocontrolled Domino Reactions for the Synthesis of Benzazepine- and Tetrahydroquinoline …

A Gupta, S Ranaut, A Kooleri, T Jandial… - The Journal of …, 2024 - ACS Publications
Palladium-catalyzed regiocontrolled intramolecular oxypalladation-initiated cascades of
multifunctional internal alkyne bearing an N-tosyl tether deliver functionalized benzazepine …

Palladium-catalyzed intramolecular oxypalladation-initiated cascade: solvent-dependent chemodivergent approach to functionalized benzazepines and …

A Gupta, T Jandial, M Karuppasamy… - Chemical …, 2023 - pubs.rsc.org
Palladium-catalyzed, solvent-dependent intramolecular oxypalladation-triggered domino
sequences of internal alkynes bearing tethered nucleophilic carboxylic ester and …

Microwave-Assisted Selective Nucleopalladation-Triggered Cascade Process: Synthesis of Highly Functionalized 3-Chloro-1H-indenes

T Jandial, A Gupta, D Tsering, KK Kapoor… - The Journal of …, 2024 - ACS Publications
A nucleopalladation-triggered cascade transformation of internal alkynes bearing an amino
nucleophile and an electrophilic enone was investigated under unconventional microwave …

A microwave-assisted intramolecular aminopalladation-triggered domino sequence: an atom economical route to 5, 10-dihydroindeno [1, 2-b] indoles

T Jandial, A Gupta, G Jan, M Karuppasamy… - Organic & …, 2023 - pubs.rsc.org
A microwave-assisted, palladium (II)-catalyzed cascade reaction of 2-alkynylanilines
tethered with an α, β-unsaturated carbonyl moiety was established to access 5, 10 …

Regioselective synthesis of tetrahydroquinolines via syn-and anti-nucleopalladation-initiated cascade processes

M Karuppasamy, P Vinoth, N Pradeep… - Organic & …, 2020 - pubs.rsc.org
Palladium (II)-catalyzed regioselective syn-chloropalladation and anti-acetoxypalladation-
initiated cascade processes were developed for the synthesis of functionalized …

Intramolecular oxypalladation-initiated domino sequence: One-pot, two-step regioselective synthesis of isoquinolines

P Vinoth, M Karuppasamy, A Gupta, S Nagarajan… - Tetrahedron, 2023 - Elsevier
A palladium-catalyzed one-pot, two-step sequential reaction of 2-alkynylarylaldehydes and
ketones was established to access isoquinolines under mild conditions. The initial palladium …