This review provides a comprehensive overview of recent advances in the supramolecular
organisation and hierarchical self-assembly of organo-functionalised hybrid …

Polyoxometalates (POMs) represent an important group of metal–oxo nanoclusters, typically
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …

During the past two decades, the search of strategies to introduce polyoxometalate (POM)
clusters as secondary building units (SBUs) to construct porous extended POM-organic …

The activation of molecular hydrogen is a key process in catalysis. Here, we demonstrate
how polyoxometalate (POM)‐based heterogeneous compounds functionalized with …

The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based
hybrid bearing remote terpyridine binding sites have been investigated. In a strongly …

Most state‐of‐art transition‐metal catalysts usually require organic ligands, which are
essential for controlling the reactivity and selectivity of reactions catalyzed by transition …

Two unprecedented examples of cluster organic frameworks (TBA) 3Cu [V6O13 (L) 2] 2·
4DEF (2)(TBA) Ag [V6O13 (L) 2] solvent (3)(TBA= tetrabutylammonium, H3L= tris …

A polyoxometalate-templated silver thiolate nanocluster,[Ag62 (StBu) 40
(Mo20O66)(Mo6O19) 3 (CH3CN) 2]·(CF3SO3) 4 (1), has been isolated, in which a giant …

The presence of oxo-ligands is one of the main required characteristics for polyoxometalates
(POMs), although some oxygen ions in a metallic environment can be replaced by other …

We report an efficient and economical amidation strategy by using a polyoxometalate-based
iron catalyst that affords the corresponding amide products in good yields. All of the …