Metal–organic framework technologies for water remediation: towards a sustainable ecosystem

M Mon, R Bruno, J Ferrando-Soria… - Journal of materials …, 2018 - pubs.rsc.org
Having access to clean water is a mandatory requirement for the proper development of
living beings. So, addressing the removal of contaminants from aquatic systems should be a …

Modern transition-metal-catalyzed carbon–halogen bond formation

DA Petrone, J Ye, M Lautens - Chemical Reviews, 2016 - ACS Publications
The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …

Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework

RW Huang, YS Wei, XY Dong, XH Wu, CX Du… - Nature …, 2017 - nature.com
Silver (i) chalcogenide/chalcogenolate clusters are promising photofunctional materials for
sensing, optoelectronics and solar energy harvesting applications. However, their instability …

Unique proton dynamics in an efficient MOF-based proton conductor

YS Wei, XP Hu, Z Han, XY Dong… - Journal of the …, 2017 - ACS Publications
Recently, research on metal–organic frameworks (MOFs) serving as a new type of proton
conductive material has resulted in many exciting achievements. However, direct …

Structural and dynamic studies of substrate binding in porous metal–organic frameworks

TL Easun, F Moreau, Y Yan, S Yang… - Chemical Society …, 2017 - pubs.rsc.org
Porous metal–organic frameworks (MOFs) are the subject of considerable research interest
because of their high porosity and capability of specific binding to small molecules, thus …

Capturing snapshots of post-synthetic metallation chemistry in metal–organic frameworks

WM Bloch, A Burgun, CJ Coghlan, R Lee, ML Coote… - Nature …, 2014 - nature.com
Post-synthetic metallation is employed strategically to imbue metal–organic frameworks
(MOFs) with enhanced performance characteristics. However, obtaining precise structural …

Crystalline Sponge Method: X‐ray Structure Analysis of Small Molecules by Post‐Orientation within Porous Crystals—Principle and Proof‐of‐Concept Studies

N Zigon, V Duplan, N Wada… - Angewandte Chemie …, 2021 - Wiley Online Library
This Review discusses, along with the historical background, the principles as well as proof‐
of‐concept studies of the crystalline sponge (CS) method, a new single‐crystal X‐ray …

Novel porous crystals with macrocycle-based well-defined molecular recognition sites

S Tashiro, M Shionoya - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Molecular recognition is one of the fundamental events in biological systems, as
typified by enzymes that enable highly efficient and selective catalytic reactions through …

Diastereoselective guest-shape dependent [2+ 2]-photodimerization of 2-cyclopenten-1-one trapped within a metal–organic framework

PA Demakov, DN Dybtsev, VP Fedin - Chemical Communications, 2023 - pubs.rsc.org
UV-induced [2+ 2] dimerization of 2-cyclopenten-1-one and 2-methyl-2-cyclopenten-1-one
was successfully carried out in a single-crystal-to-single-crystal manner within a porous …

Crystallography of encapsulated molecules

K Rissanen - Chemical Society Reviews, 2017 - pubs.rsc.org
The crystallography of supramolecular host–guest complexes is reviewed and discussed as
a part of small molecule crystallography. In these complexes, the host binds the guests …