Transition‐metal‐catalyzed oxidative annulation reactions can be used to synthesize
various benzo‐fused oxygen‐and nitrogen‐containing heterocyclic compounds from …

A versatile and readily available chiral amide directing group has been developed for the
ruthenium (II)‐catalyzed asymmetric C− H activation. Asymmetric C− H activation of the …

The first example of carboxy group assisted, remote‐selective C (sp2)− H activation with a
PdII catalyst has been developed and proceeds through a possible κ2 coordination of the …

DFT calculations of reaction mechanisms in solution have always been a hot topic,
especially for transition-metal-catalyzed reactions, in which the traditional DFT-D3 method …

The synthesis of cyclic carbonates through cycloaddition reactions between epoxides and
carbon dioxide (CO2) is an important industrial process. Metal–Organic Frameworks (MOFs) …

An asymmetric rhodium (III)-catalyzed Grignard-type addition of inert arene C–H bond to
aldehydes is reported. It provides a new strategy for the synthesis of chiral 3-substituted …

A ruthenium-catalyzed cross-dehydrogenative coupling is developed with the aid of a
weakly coordinating carboxylic acid group toward the dimerization of arene carboxylic acids …

A Ru-catalyzed selective and atom-economic ortho-C–H allylation of aromatic acids with
vinylcyclopropanes is reported. The reaction proceeds with selective cleavage of both a C …

Palladium Catalyzed Regioselective Cyclization of Arylcarboxylic Acids via Radical Intermediates
with Diaryliodonium Salts | Organic Letters ACS ACS Publications C&EN CAS Find my institution …

A strategy for amide C–N bond activation with ruthenium catalyst is described for the first
time. The in situ formed bis-cycloruthenated complexes were demonstrated to be the key …