Chemical reaction dynamics beyond the Born-Oppenheimer approximation

LJ Butler - Annual review of physical chemistry, 1998 - annualreviews.org
▪ Abstract To predict the branching between energetically allowed product channels,
chemists often rely on statistical transition state theories or exact quantum scattering …

[图书][B] The spectra and dynamics of diatomic molecules: revised and enlarged edition

H Lefebvre-Brion, RW Field - 2004 - books.google.com
This book is written for graduate students just beginning research, for theorists curious about
what experimentalists actually can and do measure, and for experimentalists bewildered by …

Recent advances in quantum theory on ro-vibrationally inelastic scattering

D Yang, H Guo, D Xie - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Molecular collisions are of fundamental importance in understanding intermolecular
interaction and dynamics. Its importance is accentuated in cold and ultra-cold collisions …

Functionalizing aromatic compounds with optical cycling centres

GZ Zhu, D Mitra, BL Augenbraun, CE Dickerson… - Nature …, 2022 - nature.com
Molecular design principles provide guidelines for augmenting a molecule with a smaller
group of atoms to realize a desired property or function. We demonstrate that these concepts …

Deceleration and electrostatic trapping of OH radicals

SYT van de Meerakker, PHM Smeets, N Vanhaecke… - Physical review …, 2005 - APS
A pulsed beam of ground state OH radicals is slowed down using a Stark decelerator and is
subsequently loaded into an electrostatic trap. Characterization of the molecular beam …

Pathway toward optical cycling and laser cooling of functionalized arenes

D Mitra, ZD Lasner, GZ Zhu, CE Dickerson… - The Journal of …, 2022 - ACS Publications
Rapid and repeated photon cycling has enabled precision metrology and the development
of quantum information systems using atoms and simple molecules. Extending optical …

Frustrated charge transfer in vibrationally inelastic Ar++N2 collisions via hard collision glory scattering

G Zhang, D Lu, M Cheng, H Guo, H Gao - Nature Communications, 2024 - nature.com
Vibrational energy transfer in collisions between ions and neutrals is a fundamental process
in interstellar media, planetary atmospheres, and plasmas. The conventional wisdom is that …

Production and deceleration of a pulsed beam of metastable NH (a1Δ) radicals

SYT van de Meerakker, I Labazan… - Journal of Physics B …, 2006 - iopscience.iop.org
We report on the production of a pulsed molecular beam of metastable NH (a 1 Δ) radicals
and present first results on the Stark deceleration of the NH (a 1 Δ, J= 2, MΩ=− 4) radicals …

Do vectors point the way to understanding energy transfer in molecular collisions?

ML Costen, S Marinakis, KG McKendrick - Chemical Society Reviews, 2008 - pubs.rsc.org
This tutorial review examines the proposition that vector properties reveal more about the
underlying potential energy surfaces controlling the inelastic exchange of energy in …

Collision-induced non-adiabatic transitions between the ion-pair states of molecular iodine: A challenge for experiment and theory

TV Tscherbul, AA Buchachenko, ME Akopyan… - Physical Chemistry …, 2004 - pubs.rsc.org
The ion-pair states of molecular iodine provide a unique system for studying the efficiency,
selectivity, and mechanisms of collision-induced non-adiabatic transitions. Non-adiabatic …