Polyferrocenylsilanes: synthesis, properties, and applications

RLN Hailes, AM Oliver, J Gwyther, GR Whittell… - Chemical Society …, 2016 - pubs.rsc.org
This in-depth review covers progress in the area of polyferrocenylsilanes (PFS), a well-
established, readily accessible class of main chain organosilicon metallopolymer consisting …

Recent progress on controlled polymerizations for functional metallopolymers

X Liu, F Liu, T Abdiryim, R Jamal - Polymer Reviews, 2024 - Taylor & Francis
Metallopolymers with precise structures and particular properties have emerged as
promising functional materials. The applications of metallopolymers depend on the unique …

Ferrocenyl glycidyl ether: a versatile ferrocene monomer for copolymerization with ethylene oxide to water-soluble, thermoresponsive copolymers

C Tonhauser, A Alkan, M Schömer, C Dingels… - …, 2013 - ACS Publications
The first ferrocene-containing epoxide monomer, ferrocenyl glycidyl ether (fcGE), is
introduced. The monomer has been copolymerized with ethylene oxide (EO). This leads to …

Sandwich complex‐containing macromolecules: property tunability through versatile synthesis

AS Abd‐El‐Aziz, C Agatemor… - Macromolecular rapid …, 2014 - Wiley Online Library
Sandwich complexes feature unique properties as the physical and electronic properties of
a hydrocarbon ligand or its derivative are integrated into the physical, electronic, magnetic …

[PDF][PDF] Redox‐Active, Organometallic Surface‐Relief Gratings from Azobenzene‐Containing Polyferrocenylsilane Block Copolymers

R Ahmed, A Priimagi, CFJ Faul, I Manners - Advanced Materials, 2012 - academia.edu
The fabrication of supramolecular photoactive materials that efficiently produce photo-
induced morphological features, exhibit robust mechanical behaviour and show orthogonal …

Electroactive linear–hyperbranched block copolymers based on linear poly (ferrocenylsilane) s and hyperbranched poly (carbosilane) s

F Wurm, S Hilf, H Frey - Chemistry–A European Journal, 2009 - Wiley Online Library
A convenient two‐step protocol is presented for synthesis of linear‐hyperbranched diblock
copolymers consisting of a linear, organometallic poly (ferrocenylsilane)(PFS) block and …

Ferrocene-Containing Multifunctional Polyethers: Monomer Sequence Monitoring via Quantitative 13C NMR Spectroscopy in Bulk

A Alkan, A Natalello, M Wagner, H Frey… - Macromolecules, 2014 - ACS Publications
Ferrocenyl glycidyl ether (fcGE) and allyl glycidyl ether (AGE) are copolymerized via living
anionic ring-opening polymerization to generate polyfunctional copolymers with molecular …

Tetragonal and helical morphologies from polyferrocenylsilane block polyelectrolytes via ionic self-assembly

R Ahmed, SK Patra, IW Hamley… - Journal of the …, 2013 - ACS Publications
The use of ionic self-assembly, a facile non-covalent approach, to access non-conventional
block copolymer morphologies, including tetragonal and helical structures, from a …

Polyferrocenylsilane homopolymers and diblock copolymers with pendant ruthenocenyl groups by photocontrolled ring-opening polymerisation

M Erhard, K Lam, M Haddow, GR Whittell… - Polymer …, 2014 - pubs.rsc.org
The strained, sila [1] ferrocenophane [{Fe (η-C5H4) 2} SiMe (η-C5H4) Ru (η-C5H5)](4) has
been prepared by the reaction of Li [(η-C5H4) Ru (η-C5H5)](8) with [{Fe (η-C5H4) 2} …

[1.1] Ferrocenophanes and Bis (ferrocenyl) Species with Aluminum and Gallium as Bridging Elements: Synthesis, Characterization, and Electrochemical Studies

B Bagh, NC Breit, K Harms, G Schatte… - Inorganic …, 2012 - ACS Publications
Salt-metathesis reactions between dilithioferrocene (Li2fc· 2/3tmeda) and intramolecularly
coordinated aluminum and gallium species RECl2 [R= 5-Me3Si-2-(Me2NCH2) C6H3; E= Al …