Biocatalysis in supercritical fluids, in fluorous solvents, and under solvent-free conditions

HR Hobbs, NR Thomas - Chemical reviews, 2007 - ACS Publications
In recent years, green chemistry has become an area of significant research interest. It is
best defined as “the utilization of a set of principles that reduces or eliminates the use or …

Lipase catalysis in ionic liquids/supercritical carbon dioxide and its applications

Y Fan, J Qian - Journal of Molecular Catalysis B: Enzymatic, 2010 - Elsevier
Ionic liquids (ILs) and supercritical carbon dioxide (SC-CO2) have been accepted as
solvents facilitating green processing by lots of scholars and researchers in recent decades …

Separation processes for organic molecules using SCF Technologies

LS Daintree, A Kordikowski, P York - Advanced drug delivery reviews, 2008 - Elsevier
Supercritical fluids have been applied for many years for the separation of solutes from
solids or solute mixtures in both exploratory and industrial applications. In the …

[PDF][PDF] Enzymatic processes in alternative reaction media: a mini review

M Ghaffari-Moghaddam, H Eslahi… - Journal of Biological …, 2015 - scholar.archive.org
Biocatalysis is a growing field in the production of fine chemicals and will most probably
increase its share in the future. Enzymatic reactions are carried out under mild conditions, ie …

Effects of Natural Osmolytes on the Protein Structure in Supercritical CO2: Molecular Level Evidence

H Monhemi, MR Housaindokht… - The Journal of Physical …, 2015 - ACS Publications
Protein instability in supercritical CO2 limits the application of this green solvent in enzyme-
catalyzed reactions. CO2 molecules act as a protein denaturant at high pressure under …

Structural behavior of Candida antarctica lipase B in water and supercritical carbon dioxide: A molecular dynamic simulation study

MR Housaindokht, MR Bozorgmehr… - The Journal of …, 2012 - Elsevier
In this study, molecular dynamic (MD) simulation is used to investigate the effect of
supercritical carbon dioxide on the structural properties of a new variant of Candida …

[HTML][HTML] Potencial catalítico de lipases ligadas ao micélio de fungos filamentosos em processos de biotransformação

DV Cortez, HF Castro, GSS Andrade - Química nova, 2017 - SciELO Brasil
Over the past decades, mycelium-bound lipase of filamentous fungus has been extensively
studied as an alternative biocatalyst in biotransformation processes. Mycelium-bound lipase …

Protein simulation in supercritical CO2: The challenge of force field

H Monhemi - Journal of Molecular Liquids, 2021 - Elsevier
Supercritical CO 2 is one of the most important green solvents for biotechnological
applications. Due to the high-pressure conditions and gas–liquid properties of the fluid, the …

Heterogeneous catalysis in supercritical media: 1. Carbon dioxide

A Kruse, H Vogel - Chemical Engineering & Technology …, 2008 - Wiley Online Library
Over the past few years, supercritical fluids have received considerable interest as reaction
media. Supercritical fluids combine properties of gases and liquids. Densities are lower than …

Enzyme is stabilized by a protection layer of ionic liquids in supercritical CO2: Insights from molecular dynamic simulation

H Monhemi, MR Housaindokht, MR Bozorgmehr… - The Journal of …, 2012 - Elsevier
In this paper, new findings about enzyme microenvironment in supercritical CO2/ionic liquid
biphasic system were obtained. All-atom molecular dynamic simulation of three systems …