Bolaamphiphilic molecules: Assembly and applications

N Nuraje, H Bai, K Su - Progress in Polymer Science, 2013 - Elsevier
This review describes the state-of-the-art scientific developments of bolaamphiphilic
molecules composed of two hydrophilic headgroups connected by a hydrophobic chain in …

Hybrid bilayer membranes as platforms for biomimicry and catalysis

T Zeng, RP Gautam, DH Ko, HL Wu… - Nature Reviews …, 2022 - nature.com
Hybrid bilayer membrane (HBM) platforms represent an emerging nanoscale bio-inspired
interface that has broad implications in energy catalysis and smart molecular devices. An …

Proton transfer dynamics control the mechanism of O2 reduction by a non-precious metal electrocatalyst

ECM Tse, CJ Barile, NA Kirchschlager, Y Li… - Nature materials, 2016 - nature.com
Many chemical and biological processes involve the transfer of both protons and electrons.
The complex mechanistic details of these proton-coupled electron transfer (PCET) reactions …

Multicopper models for the laccase active site: effect of nuclearity on electrocatalytic oxygen reduction

ECM Tse, D Schilter, DL Gray, TB Rauchfuss… - Inorganic …, 2014 - ACS Publications
Cu complexes of 2, 2′-dipicolylamine (DPA) were prepared and tested as electrocatalysts
for the oxygen reduction reaction (ORR). To study the effect of multinuclearity on the ORR …

Investigating electron-transfer processes using a biomimetic hybrid bilayer membrane system

W Ma, YL Ying, LX Qin, Z Gu, H Zhou, DW Li… - Nature …, 2013 - nature.com
Here we report a protocol to investigate the electron-transfer processes of redox-active
biomolecules in biological membranes by electrochemistry using biomimetic hybrid bilayer …

Proton switch for modulating oxygen reduction by a copper electrocatalyst embedded in a hybrid bilayer membrane

CJ Barile, ECM Tse, Y Li, TB Sobyra, SC Zimmerman… - Nature materials, 2014 - nature.com
Molecular switches gate many fundamental processes in natural and artificial systems. Here,
we report the development of an electrochemical platform in which a proton carrier switches …

Reversible Redox of NADH and NAD+ at a Hybrid Lipid Bilayer Membrane Using Ubiquinone

W Ma, DW Li, TC Sutherland, Y Li… - Journal of the …, 2011 - ACS Publications
Here, we report the reversible interconversion between NADH and NAD+ at a low
overpotential, which is in part mediated by ubiquinone embedded in a biomimetic …

Hybrid bilayer membrane: a platform to study the role of proton flux on the efficiency of oxygen reduction by a molecular electrocatalyst

A Hosseini, CJ Barile, A Devadoss… - Journal of the …, 2011 - ACS Publications
In this report, we present a novel platform to study proton-coupled electron transfer (PCET)
by controlling the proton flux using an electrode-supported hybrid bilayer membrane (HBM) …

Electrocatalytic O2 Reduction Reaction by Synthetic Analogues of Cytochrome P450 and Myoglobin: In-Situ Resonance Raman and Dynamic Electrochemistry …

S Chatterjee, K Sengupta, S Samanta, PK Das… - Inorganic …, 2013 - ACS Publications
Bioinspired electrodes have been constructed by physiabsorption of two air stable iron
porphyrin complexes, one bearing an imidazole coordination and the other bearing a …

Electrodeposition of Single‐Metal Nanoparticles on Stable Protein 1 Membranes: Application of Plasmonic Sensing by Single Nanoparticles

LX Qin, Y Li, DW Li, C Jing, BQ Chen, W Ma… - Angewandte Chemie …, 2011 - infona.pl
Light in the dark: Metal nanoparticles (M= Ag 0, Au 0, or Cu 0) were electrodeposited onto
ion‐channel pores of a stable protein 1 membrane (see picture). The metal nanoparticles …