Bifunctional hydroformylation on heterogeneous Rh-WOx pair site catalysts

I Ro, J Qi, S Lee, M Xu, X Yan, Z Xie, G Zakem… - Nature, 2022 - nature.com
Metal-catalysed reactions are often hypothesized to proceed on bifunctional active sites,
whereby colocalized reactive species facilitate distinct elementary steps in a catalytic …

[HTML][HTML] Elucidation of single atom catalysts for energy and sustainable chemical production: Synthesis, characterization and frontier science

ACM Loy, SY Teng, BS How, X Zhang… - Progress in Energy and …, 2023 - Elsevier
The emergence of single atom sites as a frontier research area in catalysis has sparked
extensive academic and industrial interest, especially for energy, environmental and …

Experimental and Theoretical Characterization of Rh Single Atoms Supported on γ-Al2O3 with Varying Hydroxyl Contents during NO Reduction by CO

AJ Hoffman, C Asokan, N Gadinas, E Schroeder… - ACS …, 2022 - ACS Publications
Oxide-supported Rh catalysts are important components of commercial three-way catalysts
for pollution abatement. Despite their universal application, many mysteries remain about …

Comparison of Heterogeneous Hydroformylation of Ethylene and Propylene over RhCo3/MCM-41 Catalysts

Z Mao, Z Xie, JG Chen - ACS Catalysis, 2021 - ACS Publications
The reaction mechanisms of heterogeneous hydroformylation of ethylene and propylene
were compared at 413–453 K using RhCo3/MCM-41 as catalysts. The reaction rates of …

Unveiling Highly Sensitive Active Site in Atomically Dispersed Gold Catalysts for Enhanced Ethanol Dehydrogenation

J Yang, J Zheng, C Dun, LJ Falling… - Angewandte Chemie …, 2024 - Wiley Online Library
Developing a desirable ethanol dehydrogenation process necessitates a highly efficient and
selective catalyst with low cost. Herein, we show that the “complex active site” consisting of …

Visible Light Photolysis at Single Atom Sites in Semiconductor Perovskite Oxides

MG Allan, RA Yang, S Marino, MJ Gordon… - Journal of the …, 2024 - ACS Publications
Designing catalysts with well-defined active sites with chemical functionality responsive to
visible light has significant potential for overcoming scaling relations limiting chemical …

Structure–Reactivity Relationship of Zeolite-Confined Rh Catalysts for Hydroformylation of Linear α-Olefins

X Dou, T Yan, W Li, C Zhu, T Chen… - Journal of the …, 2025 - ACS Publications
Substituting the molecular metal complexes used in the industrial olefin hydroformylation
process is of great significance in fundamental research and practical application. One of the …

Synthesis of atomically dispersed Rh catalysts on oxide supports via strong electrostatic adsorption and characterization by cryogenic infrared spectroscopy

C Asokan, M Xu, S Dai, X Pan… - The Journal of Physical …, 2022 - ACS Publications
Oxide-supported Rh catalysts are utilized in applications ranging from NO x reduction
reactions in automotive catalysis to hydrogenation reactions in hydrocarbon upgrading …

The structure–activity relationships of Rh/CeO2–ZrO2 catalysts based on Rh metal size effect in the three-way catalytic reactions

D Chen, W Zhao, Z Xu, Z Zhao, J Yang, Y Hou… - Nano Research, 2024 - Springer
With the continuous tightening of automotive emission regulations and the increasing
promotion of energy-efficient hybrid vehicles, new challenges have arisen for the low …

[HTML][HTML] Bioinspired Synthesis and Characterization of Dual-Function Zinc Oxide Nanoparticles from Saccharopolyspora hirsuta: Exploring Antimicrobial and …

EN Sholkamy, MAA Abdelhamid, HO Khalifa, MR Ki… - Biomimetics, 2024 - mdpi.com
Microbial synthesis offers a sustainable and eco-friendly approach for nanoparticle
production. This study explores the biogenic synthesis of zinc oxide nanoparticles (ZnO …