Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase

ST Stripp, BR Duffus, V Fourmond, C Léger… - Chemical …, 2022 - ACS Publications
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Molecular catalysts with diphosphine ligands containing pendant amines

ES Wiedner, AM Appel, S Raugei, WJ Shaw… - Chemical …, 2022 - ACS Publications
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

Artificial photosynthesis: opportunities and challenges of molecular catalysts

B Zhang, L Sun - Chemical Society Reviews, 2019 - pubs.rsc.org
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …

Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction

HB Yang, SF Hung, S Liu, K Yuan, S Miao, L Zhang… - Nature energy, 2018 - nature.com
Electrochemical reduction of CO2 to chemical fuel offers a promising strategy for managing
the global carbon balance, but presents challenges for chemistry due to the lack of effective …

Semi-biological approaches to solar-to-chemical conversion

X Fang, S Kalathil, E Reisner - Chemical Society Reviews, 2020 - pubs.rsc.org
This review presents a comprehensive summary of the recent development in semi-artificial
photosynthesis, a biological-material hybrid approach to solar-to-chemical conversion that …

Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 nd sphere interactions in catalysis

S Amanullah, P Saha, A Nayek, ME Ahmed… - Chemical Society …, 2021 - pubs.rsc.org
Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …

Single atom-based catalysts for electrochemical CO2 reduction

Q Sun, C Jia, Y Zhao, C Zhao - Chinese Journal of Catalysis, 2022 - Elsevier
Electrochemical CO 2 reduction reaction (CO 2 RR), powered by renewable energy,
emerges as a promising approach against environmental issues and energy crisis by …

Development and advancement of iridium (III)-based complexes for photocatalytic hydrogen evolution

DN Tritton, FK Tang, GB Bodedla, FW Lee… - Coordination Chemistry …, 2022 - Elsevier
Among the vast array of transition metal complexes which have been previously reported,
organometallic compounds based on iridium (III) and relevant metal complexes have been …

Nickel complexes as molecular catalysts for water splitting and CO2 reduction

JW Wang, WJ Liu, DC Zhong, TB Lu - Coordination Chemistry Reviews, 2019 - Elsevier
One of the most appealing strategies to address the problems of global warming and energy
shortage is to develop clean and sustainable energy source. To this end, considerable …