Self‐healing in supramolecular polymers

A Campanella, D Döhler… - Macromolecular rapid …, 2018 - Wiley Online Library
Adaption and self‐healing are two major principles in material science, often coupled with
the placement of supramolecular moieties within a material. Proper molecular design can …

From landfilling to vitrimer chemistry in rubber life cycle

L Imbernon, S Norvez - European Polymer Journal, 2016 - Elsevier
Cross-linked rubbers used in everyday life, thermoset by nature, represent a major
environmental problem at their end of life. The European Union has introduced a hierarchy …

Mechanically robust, self-healable, and reprocessable elastomers enabled by dynamic dual cross-links

Y Chen, Z Tang, Y Liu, S Wu, B Guo - Macromolecules, 2019 - ACS Publications
Covalent cross-linking of rubbers is essential for obtaining high resilience and
environmental resistance but prevents healing and recycling. Integrating dynamic covalent …

Design of self-healing supramolecular rubbers by introducing ionic cross-links into natural rubber via a controlled vulcanization

C Xu, L Cao, B Lin, X Liang, Y Chen - ACS applied materials & …, 2016 - ACS Publications
Introducing ionic associations is one of the most effective approaches to realize a self-
healing behavior for rubbers. However, most of commercial rubbers are nonpolar rubbers …

Recent advances of self-healing polymer materials via supramolecular forces for biomedical applications

J Xie, P Yu, Z Wang, J Li - Biomacromolecules, 2022 - ACS Publications
Noncovalent interactions can maintain the three-dimensional structures of
biomacromolecules (eg, polysaccharides and proteins) and control specific recognition in …

Dynamic ionic crosslinks enable high strength and ultrastretchability in a single elastomer

Y Miwa, J Kurachi, Y Kohbara… - Communications Chemistry, 2018 - nature.com
Maintenance-free self-healing elastomers that switch their mechanical properties on
demand would be extremely useful materials for improving the functionalities, safety, energy …

Super tough and strong self-healing elastomers based on polyampholytes

Y Peng, L Zhao, C Yang, Y Yang, C Song… - Journal of Materials …, 2018 - pubs.rsc.org
A huge challenge for developing self-healing elastomers is achieving a compromise
between mechanical properties and healing efficiency. Here, we report a class of high …

Self-healing, high-permittivity silicone dielectric elastomer

FB Madsen, L Yu, AL Skov - ACS macro letters, 2016 - ACS Publications
Currently used dielectric elastomers do not have the ability to self-heal after detrimental
events such as tearing or electrical breakdown, which are critical issues in relation to …

Self-healing polymers with nanomaterials and nanostructures

L Zhai, A Narkar, K Ahn - Nano Today, 2020 - Elsevier
Self-healing polymers have attracted a lot of attentions in the past two decades, driven by
their intriguing applications, new synthetic approaches and understanding of nanoscale …

Nano-engineered ZnO/CNF-based epoxidized natural rubber with enhanced strength for novel Self-healing glove fabrication

J Supramaniam, DYS Low, SK Wong, BF Leo… - Chemical Engineering …, 2022 - Elsevier
Rubber with excellent mechanical properties and self-healing ability could have great
applicability in the next generation of glove fabrication. Developing durable gloves with …