Mesoporous silica-based catalysts for photocatalytic CO2 reduction

Q Feng, F Wei, Z Chen, Z Huang, H Hu, F Liang… - Microporous and …, 2024 - Elsevier
Photocatalytic reduction of CO 2 to high value-added products is considered as a green and
sustainable approach to address energy and environmental issues. Mesoporous silica …

Significance of the connecting position between Zn (ii) porphyrin and Re (i) bipyridine tricarbonyl complex units in dyads for room-temperature phosphorescence and …

Y Kuramochi, Y Suzuki, S Asai, T Suzuki, H Iwama… - Chemical …, 2023 - pubs.rsc.org
We synthesized three new dyads composed of a Zn porphyrin and fac-Re (bpy)(CO) 3Br
(bpy= 2, 2′-bipyridine) units, ZnP-nBpyReBr (n= 4, 5, and 6), in which the porphyrin is …

Reduction of CO to Methanol with Recyclable Organic Hydrides

AV Müller, S Ahmad, JT Sirlin, MZ Ertem… - Journal of the …, 2024 - ACS Publications
The reaction steps for the selective conversion of a transition metal carbonyl complex to a
hydroxymethyl complex that releases methanol upon irradiation with visible light have been …

Push-pull effect–how to effectively control photoinduced intramolecular charge transfer processes in rhenium (I) chromophores with ligands of D–A or D–π–A structure

K Choroba, J Palion-Gazda, A Kryczka, E Malicka… - Dalton …, 2025 - pubs.rsc.org
Over the last five decades, diimine rhenium (I) tricarbonyl complexes have been extensively
investigated due to their remarkable and widely tuned photophysical properties. These …

Solar Light CO2 Photoreduction Enhancement by Mononuclear Rhenium(I) Complexes: Characterization and Mechanistic Insights

MA Bento, NAG Bandeira, HN Miras, AJ Moro… - Inorganic …, 2024 - ACS Publications
The catalytic efficacy of a novel mononuclear rhenium (I) complex in CO2 reduction is
remarkable, with a turnover number (TONCO) of 1517 in 3 h, significantly outperforming …

Molecular Copper–Anthraquinone Photocatalysts for Robust Hydrogen Production

H Yuan, M Ming, S Yang, K Guo, B Chen… - Journal of the …, 2024 - ACS Publications
The development of robust and inexpensive photocatalysts for H2 production under visible
light irradiation remains a significant challenge. This study presents a series of square …

Simultaneous photocatalytic biomass conversion and CO2 reduction over high crystalline oxygen-doped carbon nitride

Z Liu, J Zhang, X Li, R Cui, J Ma, R Sun - Iscience, 2023 - cell.com
Simultaneous photocatalytic biorefinery and CO 2 reduction to co-produce fuels and high
value-added chemicals have recently attracted significant attention; however …

Electronic Effect Promoted Visible-Light-Driven CO2-to-CO Conversion in a Water-Containing System

Q Feng, C Huang, Z Chen, Z Huang… - Inorganic …, 2023 - ACS Publications
The design of unsaturated nonprecious metal complexes with high catalytic performance for
photochemical CO2 reduction is still an important challenge. In this paper, four …

Further Insights into the Impact of Ligand-Localized Excited States on the Photophysics of Phenanthroline-Based Rhenium (I) Tricarbonyl Complexes

J Palion-Gazda, K Choroba, M Penkala… - Inorganic …, 2023 - ACS Publications
The present work shows the pivotal role of N-donor substituents attached to 1, 10-
phenanthroline at the 4, 7-positions in perturbation of ground-and excited-state properties of …

Etalon-Assisted Study of the Strong CO Ligand Vibrations of the fac-[Re(CO)3(bpy)(CH3CN)]+ Octahedral Complex

JV Coe, WJ Dressick, C Turro - The Journal of Physical Chemistry …, 2023 - ACS Publications
The strong CO ligand vibrations of an octahedral complex, fac-[Re (CO) 3 (bpy)(CH3CN)]+,
in acetonitrile are observed at 2040 and 1932 cm–1. Facial rhenium tricarbonyl systems …