Deep eutectic solvents: A review of fundamentals and applications

BB Hansen, S Spittle, B Chen, D Poe, Y Zhang… - Chemical …, 2020 - ACS Publications
Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by
significant depressions in melting points compared to those of the neat constituent …

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye

R Böhmer, C Gainaru, R Richert - Physics Reports, 2014 - Elsevier
In 1913 Debye devised a relaxation model for application to the dielectric properties of water
and alcohols. These hydrogen-bonded liquids continue to be studied extensively because …

Evolution of microscopic heterogeneity and dynamics in choline chloride-based deep eutectic solvents

S Spittle, D Poe, B Doherty, C Kolodziej… - Nature …, 2022 - nature.com
Deep eutectic solvents (DESs) are an emerging class of non-aqueous solvents that are
potentially scalable, easy to prepare and functionalize for many applications ranging from …

Charge-density-dominated phase behavior and viscoelasticity of polyelectrolyte complex coacervates

J Huang, FJ Morin, JE Laaser - Macromolecules, 2019 - ACS Publications
The composition dependence of the phase behavior and viscoelasticity of polyelectrolyte
complex coacervates was investigated in a series of model acrylamide copolymers with …

Nature of dielectric response of phenyl alcohols

M Tarnacka, A Czaderna-Lekka… - The Journal of …, 2023 - ACS Publications
Phenyl alcohols (PhAs) are an interesting class of materials, for which the dielectric
response reveals only the presence of single prominent Debye-like (D) relaxation …

Mesoscale organization and dynamics in binary ionic liquid mixtures

T Cosby, U Kapoor, JK Shah… - The journal of physical …, 2019 - ACS Publications
The impact of mesoscale organization on dynamics and ion transport in binary ionic liquid
mixtures is investigated by broad-band dielectric spectroscopy, dynamic-mechanical …

Dynamic-mechanical and dielectric evidence of long-lived mesoscale organization in ionic liquids

T Cosby, Z Vicars, Y Wang… - The journal of physical …, 2017 - ACS Publications
Experimental evidence of the dynamics of mesoscopic structure in room-temperature ionic
liquids a feature expected to correlate with many physicochemical properties of these …

Are hydrogen supramolecular structures being suppressed upon nanoscale confinement? The case of monohydroxy alcohols

A Talik, M Tarnacka, M Geppert-Rybczyńska… - Journal of colloid and …, 2020 - Elsevier
In this paper, the molecular dynamics, H-bonding pattern and wettability of the primary and
secondary monohydroxyalcohols, 2-ethyl-1-hexanol (2E1H), 2-ethyl-1-butanol (2E1B) and 5 …

Isomeric effects in structure formation and dielectric dynamics of different octanols

J Bolle, SP Bierwirth, M Požar, A Perera… - Physical Chemistry …, 2021 - pubs.rsc.org
The understanding of the microstructure of associated liquids promoted by hydrogen-
bonding and constrained by steric hindrance is highly relevant in chemistry, physics, biology …

How different molecular architectures influence the dynamics of H-bonded structures in glass-forming monohydroxy alcohols

M Wikarek, S Pawlus, SN Tripathy… - The Journal of …, 2016 - ACS Publications
Primary alcohols have been an active area of research since the beginning of the 20th
century. The main problem in studying monohydroxy alcohols is the molecular origin of the …