An experimental and kinetic modeling study of the oxidation of hexane isomers: Developing consistent reaction rate rules for alkanes

K Zhang, C Banyon, U Burke, G Kukkadapu… - Combustion and …, 2019 - Elsevier
Alkanes are key components in gasoline, jet and diesel fuels and considerably influence the
combustion behavior of these fuels because of their wide range of reactivity. An improved …

Experimental measurements of n-heptane flame speeds behind reflected shock waves with variable extents of pre-flame auto-ignition chemistry

L Zheng, M Figueroa-Labastida, JW Streicher… - Combustion and …, 2024 - Elsevier
The flame speeds of premixed stoichiometric n-heptane/21% O 2-79% Ar (so-called
“airgon”) flames with different extents of pre-flame auto-ignition chemistry were …

A shock tube study of n-heptane, iso-octane, n-dodecane and iso-octane/n-dodecane blends oxidation at elevated pressures and intermediate temperatures

J Shao, R Choudhary, Y Peng, DF Davidson… - Fuel, 2019 - Elsevier
Ignition delay times (IDT) of n-heptane, iso-octane, n-dodecane, and iso-octane/n-dodecane
blends, in stoichiometric mixtures with air, were measured behind reflected shock waves in a …

Experimental characterization of n-heptane low-temperature oxidation products including keto-hydroperoxides and highly oxygenated organic molecules (HOMs)

N Belhadj, R Benoit, P Dagaut, M Lailliau - Combustion and Flame, 2021 - Elsevier
The oxidation of n-heptane was performed in a jet-stirred reactor (JSR) at 10 atm, an
equivalence ratio of 0.5, and an initial fuel concentration of 1000 ppm at a residence time of …

Low-temperature oxidation of n-octane and n-decane in shock tubes: Differences in time histories of key intermediates

R Choudhary, S Clees, V Boddapati, J Shao… - Combustion and …, 2023 - Elsevier
The impact of chain length on the time histories of key intermediate species that form upon
first-stage ignition was studied experimentally in a shock tube using multi-color laser …

LT-HyChem-A physics-based chemical kinetic modeling approach for low-temperature oxidation of real fuels I: Rationale, methodology, and application to a simple …

R Choudhary, P Biswas, V Boddapati, H Wang… - Combustion and …, 2025 - Elsevier
The diversity of reactivities, intermediates, and pathways associated with the low-
temperature (low-T) oxidation of various component classes that constitute real fuels is …

Insights into engine autoignition: Combining engine thermodynamic trajectory and fuel ignition delay iso-contour

M Tao, P Zhao, JP Szybist, P Lynch, H Ge - Combustion and Flame, 2019 - Elsevier
One of the ultimate goals of chemical kinetic study is to understand and predict autoignition
in engines. In this study, utilizing toluene primary reference fuels (TPRF) as a gasoline …

Simultaneous measurements of temperature, CO, and CO2 time-history in reacting n-heptane/O2/argon mixtures blended with diethyl ether behind reflected shock …

D Zheng, D He, QD Wang, Y Ding, Z Peng - Combustion and Flame, 2022 - Elsevier
The temperature, CO, and CO 2 time-histories for the fuel-rich (equivalence ratio ϕ= 1.2 and
2.0) oxidation of n-heptane/diethyl ether/O 2/argon mixtures were measured simultaneously …

Shock tube and kinetic study on auto-ignition characteristics of methanol/n-heptane mixtures at high temperature

L Li, M Hu, W Qu, Z Gong, L Feng - Energy, 2021 - Elsevier
The development of methanol/diesel dual-fuel engines urgently requires further study on
chemical kinetic models for binary fuels. Ignition delay of lean and stoichiometric methanol/n …

Oxidation of Methane/n-Heptane Mixtures in a High-Pressure Flow Reactor

LS Thorsen, MS Thestrup Jensen, MS Pullich… - Energy & …, 2023 - ACS Publications
To evaluate the use of diesel as a pilot fuel in natural gas combustion in two-stroke maritime
engines, research on high-pressure oxidation of methane/n-heptane mixtures is of interest …