Organozinc ligands in transition metal chemistry
T Bollermann, C Gemel, RA Fischer - Coordination Chemistry Reviews, 2012 - Elsevier
Synthetic strategies and mechanistic pathways for the formation of transition metal–
organozinc compounds and their structural properties are reviewed. Herein, two groups of …
organozinc compounds and their structural properties are reviewed. Herein, two groups of …
Dihydrogen and acetylene activation by a gold (I)/platinum (0) transition metal only frustrated lewis pair
J Campos - Journal of the American Chemical Society, 2017 - ACS Publications
The first example of a frustrated Lewis pair (FLP) solely constructed around transition metal
centers is described in this work. We have focused on the established capacity of Au (I) and …
centers is described in this work. We have focused on the established capacity of Au (I) and …
What can we learn from the crystal structures of metallacarboranes?
AJ Welch - Crystals, 2017 - mdpi.com
The determination of the molecular structures of metallacarboranes by X-ray diffraction
remains critical to the development of the field, in some cases being the only viable way in …
remains critical to the development of the field, in some cases being the only viable way in …
Expansion of the (BB)[double bond splayed left] Ru metallacycle with coinage metal cations: formation of B–M–Ru–B (M= Cu, Ag, Au) dimetalacyclodiboryls
In this work, we introduce a novel approach for the selective assembly of heterometallic
complexes by unprecedented coordination of coinage metal cations to strained single …
complexes by unprecedented coordination of coinage metal cations to strained single …
Syntheses of Dinuclear and Trinuclear Hydridoplatinum Complexes with Bridging Phosphido Ligands [Pt2H2(μ-PR2)2(PEt3)2] (R = tBu, Ph) and [Pt3H2(μ-PPh2)4(PEt3)2]. Characterization of the Triangular …
M Itazaki, Y Nishihara, K Osakada - Organometallics, 2004 - ACS Publications
The reaction of Ph2PH with Pt (PEt3) 3 in 2: 1 molar ratio produces the linear triplatinum
complex [Pt3H2 (μ-PPh2) 4 (PEt3) 2](1). X-ray crystallography of 1 shows the structure of the …
complex [Pt3H2 (μ-PPh2) 4 (PEt3) 2](1). X-ray crystallography of 1 shows the structure of the …
Synthesis of Mixed-Metal (Ru− Rh) Bimetallacarboranes via exo-nido-and closo-Ruthenacarboranes. Molecular Structures of (η4-C8H12) Rh (μ-H) Ru (PPh3) 2 (η5 …
IT Chizhevsky, IA Lobanova, PV Petrovskii… - …, 1999 - ACS Publications
The reaction of exo-nido-5, 6, 10-[Cl (PPh3) 2Ru]-5, 6, 10-(μ-H) 3-10-H-7, 8-C2B9H8)(1)
with [(η4-diene) RhCl] 2 in EtOH or with [(CO) 2RhCl] 2 in MeOH in the presence of KOH …
with [(η4-diene) RhCl] 2 in EtOH or with [(CO) 2RhCl] 2 in MeOH in the presence of KOH …
Studies with the Rhenacarborane Cs[Re(CO)3(η5-7,8-C2B9H11)]: Surprising Reactivity with a Range of Metal Ligand Fragments
DD Ellis, PA Jelliss, FGA Stone - Organometallics, 1999 - ACS Publications
The rhenacarborane salt Cs [Re (CO) 3 (η 5-7, 8-C2B9H11)](1) has been synthesized in
excellent yield using a new procedure. Treatment of CH2Cl2 solutions of 1 with [RuCl2 …
excellent yield using a new procedure. Treatment of CH2Cl2 solutions of 1 with [RuCl2 …
Bridging selenocarbonyl ligands: an open and shut case
BJ Frogley, AF Hill, LJ Watson - Chemical Communications, 2019 - pubs.rsc.org
Novel bis (isoselenocarbonyl) complexes [W2Pt (μ-CSe) 2 (CO) 4 (L2)(Tp*) 2](L2=
cyclooctadiene, norbornadiene) eliminate the diene upon heating to provide [W2Pt (μ-CSe) …
cyclooctadiene, norbornadiene) eliminate the diene upon heating to provide [W2Pt (μ-CSe) …
Synthesis and Crystal Structure of the Novel Dianion [Re(CO)3(η5-7-CB10H11)]2-. Reactions with Platina- and Palladaphosphine Chlorides
I Blandford, JC Jeffery, PA Jelliss, FGA Stone - Organometallics, 1998 - ACS Publications
The salts [X] 2 [Re (CO) 3 (η5-7-CB10H11)](X= N (PPh3) 2 (2a), X= NEt3 (CH2Ph)(2b)) have
been synthesized from the reaction between [Na] 3 [nido-7-CB10H11] and [ReBr (THF) 2 …
been synthesized from the reaction between [Na] 3 [nido-7-CB10H11] and [ReBr (THF) 2 …
The Reagent [K(18-crown-6)][RuH(PPh3)2(η5-7,8-C2B9H11)] as a Precursor to New Ruthenacarborane Complexes
DD Ellis, SM Couchman, JC Jeffery, JM Malget… - Inorganic …, 1999 - ACS Publications
In ethanol the charge-compensated molecule exo-nido-ruthenacarborane [5, 6, 10-{RuCl
(PPh3) 2}-5, 6, 10-μ-(H) 3-10-H-7, 8-C2B9H8] reacts with KOH to afford the anionic closo …
(PPh3) 2}-5, 6, 10-μ-(H) 3-10-H-7, 8-C2B9H8] reacts with KOH to afford the anionic closo …