Applications of alkyl orthoesters as valuable substrates in organic transformations, focusing on reaction media

Z Khademi, K Nikoofar - RSC advances, 2020 - pubs.rsc.org
In this review we focus on applications of alkyl orthoesters as valuable and efficient
substrates to perform various classes of two-component and multi-component organic …

Intramolecular Schmidt reactions of alkyl azides with ketones: scope and stereochemical studies

GL Milligan, CJ Mossman, J Aube - Journal of the American …, 1995 - ACS Publications
The intramolecular Schmidt reaction of alkyl azides and ketones has been demonstrated.
The reaction is proposed to occur via initial attack of an azide on a ketone activated by a …

Titanium tetrachloride-mediated reactions of alkyl azides with cyclic ketones

J Aube, GL Milligan, CJ Mossman - The Journal of Organic …, 1992 - ACS Publications
The reaction of cyclic ketones with alkyl azides to afford N-alkyl lactams can be effected by
TiCl4. The Schmidt reaction of ketones with hydrazoic acid is an important method for the …

Intramolecular Schmidt reactions of alkyl azides with ketals and enol ethers

CJ Mossman, J Aubé - Tetrahedron, 1996 - Elsevier
The ketals or enol ethers of 1, 5-azidoketones were converted into lactams using a two-
stage process. Treatment of the ketals and enol ethers with acid (trifluoroacetic acid, triflic …

[PDF][PDF] Reactivity features of cyclododecanone.

HH Zoorob, MS Elsherbini… - ARKIVOC: Online Journal …, 2011 - arkat-usa.org
To use the template, select (highlight) the section of the template to be replaced ( Page 1 Reviews
and Accounts ARKIVOC 2011 (i) 429-495 Reactivity features of cyclododecanone Hanafi H …

7-Hydroxynadic acid: a new end cap for improved oxidation resistance in addition polyimides

MAB Meador, JC Johnston, AA Frimer… - Chemistry of …, 2001 - ACS Publications
We consider possible replacements for the norbornenyl end cap in addition polyimides that
should favor bridge degradation and lead to lower weight loss in the resin system. Our …

Cationic carbon to nitrogen rearrangements in the reactions of N-(sulfonyloxy) amines with aldehydes

RV Hoffman, JM Salvador - The Journal of Organic Chemistry, 1992 - ACS Publications
A series of aromatic and aliphatic aldehydes was reacted with JV-((p-nitrobenzenesulfonyl)
oxy) methylamine in chloroform. Products resulting from both carbon migration and hydride …

Molecular Rearrangements

AW Murray - Org. React. Mech, 2003 - Wiley Online Library
A theoretical study has been carried out on the reactivity of the phenyl cation with a propyl
group at the ortho position. 1 Alkenyl (phenyl) iodonium tetrafluoroborates have been found …

Synthesis, Spectral Characterization, and In Vitro Cytotoxicity of N‐2′‐Hydroxyethyl‐Substituted Azacholestanes Prepared from 6‐Oxocholestanes by Modified …

SAA Nami, S Khan, M Alam, M Mushfiq… - Journal of …, 2013 - Wiley Online Library
The present paper reports the synthesis and spectroscopic characterization of few N‐2′‐
hydroxyethyl‐substituted azacholestanes using BF3‐OEt2, TiCl4, SnCl4, and H2SO4 as …

[PDF][PDF] Potassium 4-nitrophenylsulfonate monohydrate

AJ Blatch, JAK Howard, MR Probert… - … Section E: Structure …, 2006 - journals.iucr.org
Potassium 4-nitrophenylsulfonate monohydrate Page 1 metal-organic papers Acta Cryst. (2006).
E62, m741–m743 doi:10.1107/S1600536806007835 Blatch et al. K+ÁC6H4NO5SÀÁH2O …