Halogen Bonds of Halogen (I) Ions─ Where Are We and Where to Go?
LHE Wieske, M Erdelyi - Journal of the American Chemical …, 2023 - ACS Publications
Halenium ions, X+, are particularly strong halogen-bond donors that interact with two Lewis
bases simultaneously to form linear [D··· X··· D]+-type halonium complexes. Their three …
bases simultaneously to form linear [D··· X··· D]+-type halonium complexes. Their three …
Halogen bonds of halonium ions
L Turunen, M Erdélyi - Chemical Society Reviews, 2020 - pubs.rsc.org
Due to their electron deficiency, halonium ions act as particularly strong halogen bond
donors. By accepting electrons in both lobes of their empty p-orbital, they are capable of …
donors. By accepting electrons in both lobes of their empty p-orbital, they are capable of …
Halogen‐Bonded Organic Framework (XOF) Based on Iodonium‐Bridged N⋅⋅⋅I+⋅⋅⋅N Interactions: A Type of Diphase Periodic Organic Network
G Gong, S Lv, J Han, F Xie, Q Li, N Xia… - Angewandte …, 2021 - Wiley Online Library
Due to the fascinating structures and wide applications, porous materials with open
frameworks have attracted more and more attentions. Herein, a novel two‐dimensional (2D) …
frameworks have attracted more and more attentions. Herein, a novel two‐dimensional (2D) …
Halogen‐Bonded Organic Frameworks (XOFs) Based on N⋅⋅⋅Br+⋅⋅⋅N Bonds: Robust Organic Networks Constructed by Fragile Bonds
X Bai, Z Tian, H Dong, N Xia, J Zhao… - Angewandte Chemie …, 2024 - Wiley Online Library
Organic frameworks face a trade‐off between the framework stability and the bond
dynamics, which necessitates the development of innovative linkages that can generate …
dynamics, which necessitates the development of innovative linkages that can generate …
X⋅⋅⋅ X Halogen Bond‐Induced Supramolecular Helices
Y Xu, A Hao, P Xing - Angewandte Chemie International …, 2022 - Wiley Online Library
The halogen bond is the attractive interaction between the electrophilic region of a halogen
atom and the nucleophilic region of another molecular entity, emerging as a favorable …
atom and the nucleophilic region of another molecular entity, emerging as a favorable …
N−X⋅⋅⋅O−N Halogen Bonds in Complexes of N‐Haloimides and Pyridine‐N‐oxides: A Large Data Set Study
R Puttreddy, JM Rautiainen, S Yu… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract N− X⋅⋅⋅− O− N+ halogen‐bonded systems formed by 27 pyridine N‐oxides
(PyNOs) as halogen‐bond (XB) acceptors and two N‐halosuccinimides, two N …
(PyNOs) as halogen‐bond (XB) acceptors and two N‐halosuccinimides, two N …
Supramolecular axial chirality in [N–I–N]+-type halogen bonded dimers
S An, A Hao, P Xing - Chemical Science, 2023 - pubs.rsc.org
Axial chiral molecules are extensively used as skeletons in ligands for asymmetric catalysis
and as building blocks of chiroptical materials. Designing axial chirality at the …
and as building blocks of chiroptical materials. Designing axial chirality at the …
Halogen bonding in solution: NMR spectroscopic approaches
D von der Heiden, A Vanderkooy, M Erdelyi - Coordination Chemistry …, 2020 - Elsevier
A halogen bond is a non-covalent interaction between an electron deficient halogen atom
and a nucleophilic region of a molecule [1]. The halogen bearing molecule is referred to as …
and a nucleophilic region of a molecule [1]. The halogen bearing molecule is referred to as …
[N···I···N]+ Type Halogen-Bonding-Driven Supramolecular Helical Polymers with Modulated Chirality
S An, A Hao, P Xing - ACS nano, 2022 - ACS Publications
The [N··· I··· N]+ type halogen bond has been utilized to synthesize supramolecular
architectures, while the applications in constructing helical motifs and modulating …
architectures, while the applications in constructing helical motifs and modulating …
Asymmetric [N–I–N]+ halonium complexes
The first asymmetric halogen-bonded iodonium complexes [I (py)(4-DMAP)] PF6 (2c) and [I
(py)(4-Etpy)] PF6 (2e) were prepared via [N–Ag–N]+→[N–I–N]+ cation exchange of their …
(py)(4-Etpy)] PF6 (2e) were prepared via [N–Ag–N]+→[N–I–N]+ cation exchange of their …