Halogen bonding and chalcogen bonding mediated sensing

R Hein, PD Beer - Chemical Science, 2022 - pubs.rsc.org
Sigma–hole interactions, in particular halogen bonding (XB) and chalcogen bonding (ChB),
have become indispensable tools in supramolecular chemistry, with wide-ranging …

Unravelling the potential of sigma hole-assisted co-crystallization: Highlighting recent developments

R Siddiqui, J Rani, HM Titi, R Patra - Coordination Chemistry Reviews, 2024 - Elsevier
In the past several decades, the field of cocrystal engineering has developed into a vital
research topic in supramolecular chemistry, holding the foremost scope in crystal …

Selective potassium chloride recognition, sensing, extraction, and transport using a chalcogen-bonding heteroditopic receptor

A Docker, I Marques, H Kuhn, Z Zhang… - Journal of the …, 2022 - ACS Publications
Chalcogen bonding (ChB) is rapidly rising to prominence in supramolecular chemistry as a
powerful sigma (σ)-hole-based noncovalent interaction, especially for applications in the …

Multistate redox-switchable ion transport using chalcogen-bonding anionophores

A Docker, TG Johnson, H Kuhn, Z Zhang… - Journal of the …, 2023 - ACS Publications
Synthetic supramolecular transmembrane anionophores have emerged as promising
anticancer chemotherapeutics. However, key to their targeted application is achieving …

Modulating chalcogen bonding and halogen bonding sigma‐hole donor atom potency and selectivity for halide anion recognition

A Docker, CH Guthrie, H Kuhn… - Angewandte Chemie …, 2021 - Wiley Online Library
A series of acyclic anion receptors containing chalcogen bond (ChB) and halogen bond
(XB) donors integrated into a neutral 3, 5‐bis‐triazole pyridine scaffold are described, in …

Halogen bonding tetraphenylethene anion receptors: Anion‐induced emissive aggregates and photoswitchable recognition

A Docker, X Shang, D Yuan, H Kuhn… - Angewandte Chemie …, 2021 - Wiley Online Library
A series of tetraphenylethene (TPE) derivatives functionalized with highly potent electron‐
deficient perfluoroaryl iodo‐triazole halogen bond (XB) donors for anion recognition are …

Exploiting the Catenane Mechanical Bond Effect for Selective Halide Anion Transmembrane Transport

H Min Tay, TG Johnson, A Docker… - Angewandte Chemie …, 2023 - Wiley Online Library
The first examples of [2] catenanes capable of selective anion transport across a lipid bilayer
are reported. The neutral halogen bonding (XB)[2] catenanes were prepared via a chloride …

Sulfonium and selenonium salts as noncovalent organocatalysts for the multicomponent Groebke–Blackburn–Bienaymé reaction

MV Il'in, AS Novikov, DS Bolotin - The Journal of Organic …, 2022 - ACS Publications
Sulfonium and selenonium salts, represented by S-aryl dibenzothiophenium and Se-aryl
dibenzoselenophenium triflates, were found to exhibit remarkable catalytic activity in the …

Anti‐Hofmeister Anion Selectivity via a Mechanical Bond Effect in Neutral Halogen‐Bonding [2] Rotaxanes

A Docker, YC Tse, HM Tay, AJ Taylor… - Angewandte Chemie …, 2022 - Wiley Online Library
Exceptionally strong halogen bonding (XB) donor‐chloride interactions are exploited for the
chloride anion template synthesis of neutral XB [2] rotaxane host systems which contain …

A Self‐Assembled Cage Binding Iodide Anions over Other Halide Ions in Water

Y Wu, C Zhang, S Fang, D Zhu, Y Chen… - Angewandte …, 2022 - Wiley Online Library
A triangular‐prism shaped cage was self‐assembled by the formation of a dynamic covalent
bond, namely a hydrazone, in acidic aqueous solution. The hexacationic host bears a …