Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Transition metal (TM)‐catalyzed difunctionalization of unactivated olefins with two carbon‐
based entities is a powerful method to construct complex molecular architectures rapidly …

Alkene dicarbofunctionalizations enable the streamlined construction of aliphatic structures
and have thus been the subject of intense research efforts. Despite significant progress …

A nickel-catalyzed, enantioselective, three-component fluoroalkylarylation of unactivated
alkenes with aryl halides and perfluoroalkyl iodides has been described. This cross …

An unprecedented asymmetric acyl-carbamoylation of pendant alkenes tethered on aryl
carbamic chlorides with both aliphatic and aromatic aldehydes has been developed via the …

Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

A Ni-catalyzed enantioselective reductive diarylation of activated alkenes by domino
cyclizative/cross-coupling of two aryl bromides is developed. This reaction proceeds under …

A nickel‐catalyzed asymmetric diarylation reaction of vinylarenes enables the preparation of
chiral α, α, β‐triarylated ethane scaffolds, which exist in a number of biologically active …

The use of combined Heck carbometalation and cross-coupling remains one of the most
powerful ways for the difunctionalization of unactivated olefins with organometallic reagents …

As a straightforward strategy for rapidly increasing molecular complexity,
dicarbofunctionalization of alkenes has attracted substantial interests of organic synthesis …