The highlight of this article is the recent progress in the state-of-the-art synthetic design and
isolation of artificial porphyrinoids by swapping pyrrole component (s) with diverse …

Novel interrupted π-conjugated macrocycles derived from expanded porphyrinoids were
synthesized, and their unique reactivity was investigated in this work. The specific porphyrin …

An N‐confused phlorin isomer bearing a dipyrrin moiety at the α‐position of the confused
pyrrole ring (1) was synthesized. PdII and BIII coordination at the peripheral prodigiosin‐like …

An anthracene‐containing meso‐fused carbaporphyrin, which has extended π‐conjugation
pathways as compared to the corresponding naphthalene‐containing carbaporphyrin, has …

Calix [n] porphyrinoids containing both sp2 and sp3 meso‐carbons can bind metals like
porphyrinoids and anions like calix [n] pyrroles. Thus, calix [n] porphyrinoids are hybrid …

Fused porphyrinoids have received increasing interest in light of their extended conjugation
and unique coordination behavior. On the basis of our previously reported multiply fused …

Conjugate addition of ethanol and subsequent oxidation with [bis (trifluoroacetoxy) iodo]
benzene (PIFA) allowed for the inner ethoxylation of 3‐oxo‐N‐confused …

Sulfolenopyrrole-based normal and N-confused phlorins have been constructed to address
the seldom touched phlorin functionalization and simultaneously explore the effect of the …

An N-confused hexapyrrolic phlorinoid 1 and its isomer N-fused hexapyrrolic phlorinoid 2
were synthesized through [4+ 2] condensation. Both 1 and 2 can be readily transformed into …

A doubly N-confused phlorin and phlorinone analogue were synthesized from a β, β′-
linked dipyrromethane precursor and characterized by means of NMR and UV-Vis …