Sustainable developments in polyolefin chemistry: Progress, challenges, and outlook

XY Wang, Y Gao, Y Tang - Progress in Polymer Science, 2023 - Elsevier
Polyolefins are the largest-scale synthetic plastics and play a key role in modern society.
Their production consumes huge amounts of fossil-derived monomer feedstocks, which …

Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

Chemically recyclable polyolefin-like multiblock polymers

Y Zhao, EM Rettner, KL Harry, Z Hu, J Miscall… - Science, 2023 - science.org
Polyolefins are the most important and largest volume plastics produced. Unfortunately, the
enormous use of plastics and lack of effective disposal or recycling options have created a …

Investigation into the reaction pathways and catalyst deactivation for polyethylene hydrogenolysis over silica-supported cobalt catalysts

SS Borkar, R Helmer, S Panicker… - … Sustainable Chemistry & …, 2023 - ACS Publications
Chemical repurposing has emerged as a promising route to valorize “end-of-use” plastic
waste and mitigate its release to the environment. In this work, we applied silica-supported …

Beyond conventional degradation: catalytic solutions for polyolefin upcycling

L Gan, Z Dong, H Xu, H Lv, G Liu, F Zhang… - CCS …, 2024 - chinesechemsoc.org
Polyolefins (POs, ie, polyethylenes, ethylene/α-olefin copolymers, and polypropylenes) are
the most ubiquitous synthetic macromolecular materials in modern life. Their widespread …

Circular olefin copolymers made de novo from ethylene and α-olefins

XW Han, X Zhang, Y Zhou, A Maimaitiming… - Nature …, 2024 - nature.com
Ethylene/α-olefin copolymers are produced in huge scale and widely used, but their after-
use disposal has caused plastic pollution problems. Their chemical inertness made …

Isoreticular Metal–Organic Frameworks Confined Mononuclear Ru-Hydrides Enable Highly Efficient Shape-Selective Hydrogenolysis of Polyolefins

M Chauhan, N Antil, B Rana, N Akhtar, C Thadhani… - JACS Au, 2023 - ACS Publications
Upcycling nonbiodegradable plastics such as polyolefins is paramount due to their ever-
increasing demand and landfills after usage. Catalytic hydrogenolysis is highly appealing to …

Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity

BC Vance, S Najmi, PA Kots, C Wang, S Jeon… - JACS Au, 2023 - ACS Publications
Earth-abundant metals have recently been demonstrated as cheap catalyst alternatives to
scarce noble metals for polyethylene hydrogenolysis. However, high methane selectivities …

Efficient and selective dual-pathway polyolefin hydro-conversion over unexpectedly bifunctional M/TiO2-anatase catalysts

L Chen, JB Moreira, LC Meyer, J Szanyi - Applied Catalysis B …, 2023 - Elsevier
The huge scale of plastic waste generation and its environmental consequences drive the
demands for catalytic plastic upcycling processes. Here, we report efficient polypropylene …

Treasuring trash: Pt/SrTiO3 catalysts process plastic waste into high-value materials

IL Peczak, RM Kennedy, RA Hackler, B Lee, M Meirow… - Matter, 2023 - cell.com
Single-use plastics are ubiquitous throughout modern society because they have properties
that make them desirable in a wide variety of applications, including low cost of production …