Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

In contrast with the well-established enantioconvergent radical C (sp 3)–C cross-coupling of
racemic secondary alkyl electrophiles, the corresponding coupling of tertiary electrophiles to …

Although α-chiral C (sp 3)–S bonds are of enormous importance in organic synthesis and
related areas, the transition-metal-catalysed enantioselective C (sp 3)–S bond construction …

The enantioconvergent C (sp3)–N cross-coupling of racemic alkyl halides with (hetero)
aromatic amines represents an ideal means to afford enantioenriched N-alkyl (hetero) …

Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Continued development of the Sonogashira coupling has made it a well established and
versatile reaction for the straightforward formation of C–C bonds, forging the carbon …

Recent developments in catalytic asymmetric aldol reactions have been summarized.
Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl …

Abstract The Michaelis–Becker reaction of H-phosphonates with alkyl halides represents an
ideal means for synthesizing alkyl phosphorous compounds. However, the …

The copper-catalyzed enantioselective intermolecular radical 1, 2-carboamination of
alkenes with readily accessible alkyl halides is an appealing strategy for producing chiral …