Rational development of molecular earth-abundant metal complexes for electrocatalytic hydrogen production

JD McCool, S Zhang, I Cheng, X Zhao - Chinese Journal of Catalysis, 2022 - Elsevier
For public health and environmental protection reasons, there is an urgent need to replace
traditional fossil fuels with clean and renewable sources. Electrochemical splitting of water …

Ligand-Centered Hydrogen Evolution with Ni (II) and Pd (II) DMTH

CA Phipps, DT Hofsommer, MJ Toda… - Inorganic …, 2022 - ACS Publications
In this study, we report a pair of electrocatalysts for the hydrogen evolution reaction (HER)
based on the noninnocent ligand diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2 …

Utilizing charge effects and minimizing intramolecular proton rearrangement to improve the overpotential of a thiosemicarbazonato zinc HER catalyst

SP Cronin, AA Mamun, MJ Toda, MS Mashuta… - Inorganic …, 2019 - ACS Publications
The zinc (II) complex of diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2-hydrazonepyridine),
ZnL1 (1), was prepared and evaluated as a precatalyst for the hydrogen evolution reaction …

Designing a Phenalenyl-Based Dinuclear Ni (II) Complex: An Electrocatalyst with Two Single Ni Sites for the Oxygen Evolution Reaction (OER)

N Kamboj, RK Metre - Inorganic Chemistry, 2024 - ACS Publications
A new dinuclear Ni (II) complex 1,[Ni2II (dtbh-PLY) 2], is synthesized from 9-(2-(3, 6-di-tert-
butyl-2-hydroxybenzylidene) hydrazineyl)-1 H-phenalen-1-one, dtbh-PLYH2 ligand, and …

Novel Nickel (II) complex bearing acenaphthenequinone based thiosemicarbazone bis-Schiff Base: Synthesis, characterization, linkage isomers, antitumor activity …

M Ghassemzadeh, ME Moghadam, M Saeidifar… - Journal of Molecular …, 2024 - Elsevier
The synthesis of a new nickel (II) coordination complex bearing acenaphthenequinone bis
(thiosemicarbazone),[NiL], a N 2 S 2 tetradentate bis-Schiff base ligand (H 2 L), under reflux …

Modulating the reduction potential and ligand basicity of Ni (II) HER catalysts with highly conjugated N2S2 ligands

M Paudel, S Karki, K Bajaj, DT Hofsommer… - Inorganica Chimica …, 2024 - Elsevier
Molecular catalysts with N 2 S 2 chelates and earth abundant metals have been used in
different applications. With their versatile nature to modulate activity through changes in the …

Selenium tethered copper phthalocyanine hierarchical aggregates as electrochemical hydrogen evolution catalysts

I Sakthinathan, M Mahendran, K Krishnan… - Sustainable Energy & …, 2021 - pubs.rsc.org
The development of non-precious metal catalysts for the hydrogen evolution reaction (HER)
with excellent stability and adequate performance characteristics in an acid environment is …

Unravelling the potential of disposable and modifiable pencils as catalyst supports for hydrogen evolution reaction

M Paudel, B Daniels, AM Arts, A Gupta… - New Journal of …, 2022 - pubs.rsc.org
Increasing fossil fuel demands and growing concerns of global climate change have
stimulated interest in the development of electrocatalysts to produce H2 as an alternative …

Immobilization strategies for carbon electrode materials

P Sarkar, A Chaturvedi, RK Gautam, N Devi, S Sinha - 2023 - books.rsc.org
Carbon electrodes are of great interest in analytical and industrial electrochemistry. In
addition, the ''classical''carbon materials such as graphite, glassy carbon and carbon black …

Electrochemistry of anode materials in lithium-and sodium-ion batteries

B Ali - 2023 - books.rsc.org
Lithium-ion batteries (LIBs) have a high energy and power density, making them attractive
for electric vehicles (EVs) and portable electronic devices. In commercially available LIBs …