Lariat ethers: from simple sidearms to supramolecular systems

GW Gokel - Chemical Society Reviews, 1992 - pubs.rsc.org
Until the 196Os, complexation of alkali and alkaline earth metal cations was problematic.
Although such Ca2+ binders as ethylenediaminetetraacetic acid, EDTA, were well known …

Experimental evidence for alkali metal cation− π interactions

GW Gokel, SL De Wall… - European journal of …, 2000 - Wiley Online Library
The interaction of alkali metal ions with arenes such as benzene or substituted benzenes
has been documented in a variety of ways. This paper reviews the experimental evidence …

12-, 15-, and 18-Membered-ring nitrogen-pivot lariat ethers: syntheses, properties, and sodium and ammonium cation binding properties

RA Schultz, BD White, DM Dishong… - Journal of the …, 1985 - ACS Publications
Nitrogen-pivot lariat ethers of varying ring sizes can be prepared by cyclization of an amine
or appropriately substituted diol. Twelve-membered-ring nitrogen-pivot lariat ethers were …

Macrocyclic polyethers as probes to assess and understand alkali metal cation-π interactions

GW Gokel, LJ Barbour, L Stephen… - Coordination Chemistry …, 2001 - Elsevier
Cation-π interactions of alkali metals with arenes have been known in the gas phase for two
decades but solid-state structural data have become available only recently. The quest for …

Comprehensive coordination chemistry of alkali and alkaline earth cations with macrocyclic multidentates: latest position

AV Bajaj, NS Poonia - Coordination chemistry reviews, 1988 - Elsevier
The electrically neutral compounds (including solvents and crowns) have been denoted by
capital letters while the anions use lower-case letters; the crown-related macrocycles have …

Solid-state structural chemistry of lariat ether and BiBLE cation complexes: metal-ion identity and coordination number determine cavity size

RD Gandour, FR Fronczek, VJ Gatto… - Journal of the …, 1986 - ACS Publications
X-ray crystal structure data are presented for K+ complexes of A'-allylmonoaza-18-crown-6
(1) monohydrate [K+ C 5-allyl-H20], 7V, 7V'-bis (3-oxabutyl) diaza-18-crown-6 (2)[K+ C1-22 …

Complexes of tridentate and pentadentate macrocyclic ligands

R Bhula, P Osvath, DC Weatherburn - Coordination chemistry reviews, 1988 - Elsevier
Rangoon, Burma, and Calcutta, India, are somewhat unlikely places to begin a review of the
chemistry of tridentate and pentadentate macrocyclic complexes. However, in 1937 Peacock …

Lipophilic bis (monoaza crown ether) derivatives: synthesis and cation-complexing properties

H Sakamoto, K Kimura, Y Koseki… - The Journal of …, 1986 - ACS Publications
Eleven lipophilic bis (monoaza crown ether) derivatives [1 and 2 (= 0-3) and 3 (= 1-3)] were
synthesized, in which two monoaza crown ethers with 9-, 12-, 15-, or 18-membered rings are …

Novel azacrown ether-containing spiro [indoline-2, 3′-naphthoxazines]: design, synthesis and cation-dependent photochromism

OA Fedorova, SP Gromov, YV Pershina… - Journal of the …, 2000 - pubs.rsc.org
Novel spironaphthoxazine compounds with an aza-15-crown-5 ether fragment at position
5′ or 9′ of the naphthalene ring were synthesised. Spectrokinetic measurements showed …

Biomimetic Membrane Transport via Designed Macrocyclic Host Molecules

H Tsukube - Journal of coordination chemistry, 1987 - Taylor & Francis
Biomimetic approaches to naturally occurring ion transport were discussed. Selective
transport systems of alkali, alkaline earth, heavy, and transition metal cations as well as …