[HTML][HTML] Recent advances in electrochemical removal and recovery of phosphorus from water: A review
Phosphorus (P) is an essential microelement for biota. Phosphate minerals obtained
through subsurface mining are the main sources of P. Phosphate-bearing rocks are …
through subsurface mining are the main sources of P. Phosphate-bearing rocks are …
Reactive high-spin iron (IV)-oxo sites through dioxygen activation in a metal–organic framework
In nature, nonheme iron enzymes use dioxygen to generate high-spin iron (IV)= O species
for a variety of oxygenation reactions. Although synthetic chemists have long sought to …
for a variety of oxygenation reactions. Although synthetic chemists have long sought to …
Highly efficient peroxymonosulfate activation on Fe-NC catalyst via the collaboration of low-coordinated Fe-N structure and Fe nanoparticles for enhanced organic …
W Song, X Xiao, G Wang, X Dong, X Zhang - Journal of Hazardous …, 2023 - Elsevier
Supporting Fe catalysts on N doped carbon (Fe-NC) renders a promising way towards
peroxymonosulfate (PMS) activation for water decontamination, but constructing high …
peroxymonosulfate (PMS) activation for water decontamination, but constructing high …
Highly selective synthesis of surface FeIV=O with nanoscale zero-valent iron and chlorite for efficient oxygen transfer reactions
High-valent iron-oxo species (FeIV= O) has been a long-sought-after oxygen transfer
reagent in biological and catalytic chemistry but suffers from a giant challenge in its gentle …
reagent in biological and catalytic chemistry but suffers from a giant challenge in its gentle …
Coordination dynamics of iron center enables the C–H bond activation: QM/MM insight into the catalysis of hydroxyglutarate synthase (HglS)
Y Fu, B Wang, Z Cao - Journal of Catalysis, 2023 - Elsevier
Abstract Hydroxyglutarate synthase (HglS) from Pseudomonas putida is an iron (II)
dependent non-heme oxygenase, which is responsible for the biodegradation of 2 …
dependent non-heme oxygenase, which is responsible for the biodegradation of 2 …
Synchronously improved permeability, selectivity and fouling resistance of Fe-NC functionalized ceramic catalytic membrane for effective water treatment: The critical …
Y Gao, G Wang, X Wang, X Dong, X Zhang - Journal of Hazardous …, 2024 - Elsevier
Constructing catalytic membrane simultaneously displaying high permeability, selectivity
and antifouling performance in water treatment remains challenging. Herein, the surface and …
and antifouling performance in water treatment remains challenging. Herein, the surface and …
New Frontiers in Nonheme Enzymatic Oxyferryl Species
Non‐heme mononuclear iron dependent (NHM− Fe) enzymes exhibit exceedingly diverse
catalytic reactivities. Despite their catalytic versatilities, the mononuclear iron centers in …
catalytic reactivities. Despite their catalytic versatilities, the mononuclear iron centers in …
NMR and Mössbauer Studies Reveal a Temperature-Dependent Switch from S = 1 to 2 in a Nonheme Oxoiron(IV) Complex with Faster C–H Bond Cleavage Rates
S= 2 FeIV═ O centers generated in the active sites of nonheme iron oxygenases cleave
substrate C–H bonds at rates significantly faster than most known synthetic FeIV═ O …
substrate C–H bonds at rates significantly faster than most known synthetic FeIV═ O …
Data-driven ligand field exploration of Fe (iv)–oxo sites for C–H activation
High-valent Fe (IV)–oxo intermediates, found in enzyme active sites, are excellent targets for
biomimetic design of molecular catalysts for C–H bond activation. C–H bonds in inert …
biomimetic design of molecular catalysts for C–H bond activation. C–H bonds in inert …
In-situ Generation of Highly-Reactive FeIV= O and Its Contribution during CH4 Conversion to CH3OH
H Tang, Y Ma, G Zheng, C Zhu, M Wang, Y Lu… - Applied Catalysis B …, 2024 - Elsevier
Photocatalytic CH 4 conversion to CH 3 OH under mild conditions is undoubtedly an efficient
strategy to realize CH 4 upgrading. In this work, in-situ formed highly reactive Fe IV= O …
strategy to realize CH 4 upgrading. In this work, in-situ formed highly reactive Fe IV= O …