Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

New strategies for the preparation of sinter‐resistant metal‐nanoparticle‐based catalysts

L Wang, L Wang, X Meng, FS Xiao - Advanced Materials, 2019 - Wiley Online Library
Supported metal nanoparticles are widely used as catalysts in the industrial production of
chemicals, but still suffer from deactivation because of metal leaching and sintering at high …

Metal affinity of support dictates sintering of gold catalysts

JC Liu, L Luo, H Xiao, J Zhu, Y He… - Journal of the American …, 2022 - ACS Publications
Sintering during heterogeneous catalytic reactions is one of the most notorious deactivation
channels in catalysts of supported metal nanoparticles. It is therefore critical to understand …

The physical chemistry and materials science behind sinter-resistant catalysts

Y Dai, P Lu, Z Cao, CT Campbell, Y Xia - Chemical Society Reviews, 2018 - pubs.rsc.org
Catalyst sintering, a main cause of the loss of catalytic activity and/or selectivity at high
reaction temperatures, is a major concern and grand challenge in the general area of …

Constructing morphologically stable supported noble metal catalysts in heterogeneous catalysis: Mechanisms and strategies

Y Xiao, J Zhang, T Liu, M Xu, Y Dong, CA Wang - Nano Energy, 2024 - Elsevier
Supported noble metal catalysts have a wide range of applications in chemistry synthesis,
energy conversion, and environmental protection. However, the sintering of metal particles …

Mechanistic understanding and the rational design of sinter-resistant heterogeneous catalysts

ED Goodman, JA Schwalbe, M Cargnello - ACS Catalysis, 2017 - ACS Publications
The activity and selectivity of heterogeneous catalysts are strong functions of the
morphology of the catalytic active phase, which governs both the density and type of active …

Chemical and thermal sintering of supported metals with emphasis on cobalt catalysts during Fischer–Tropsch synthesis

M Rahmati, MS Safdari, TH Fletcher, MD Argyle… - Chemical …, 2020 - ACS Publications
This comprehensive critical review combines, for the first time, recent advances in nanoscale
surface chemistry, surface science, DFT, adsorption calorimetry, and in situ XRD and TEM to …

Direct In Situ TEM Visualization and Insight into the Facet‐Dependent Sintering Behaviors of Gold on TiO2

W Yuan, D Zhang, Y Ou, K Fang, B Zhu… - Angewandte …, 2018 - Wiley Online Library
Preventing sintering of supported nanocatalysts is an important issue in nanocatalysis. A
feasible way is to choose a suitable support. However, whether the metal–support …

Review and Perspectives of Enhancement in the Catalytic Stability for the Complete Combustion of CO, CH4, and Volatile Organic Compounds

Y Feng, Y Liu, H Dai, J Deng - Energy & Fuels, 2023 - ACS Publications
As typical air pollutants, CO, CH4, and volatile organic compounds (VOCs) have received
great attention due to their negative impact on the environment and human health …

Facile fabrication of Au/Fe3O4 nanocomposites as excellent nanocatalyst for ultrafast recyclable reduction of 4-nitropheol

Y Yang, K Jiang, J Guo, J Li, X Peng, B Hong… - Chemical Engineering …, 2020 - Elsevier
A highly efficient Au/Fe 3 O 4 nanocatalyst is fabricated by using a seed deposition method,
and is characterized by XRD, TEM, EDS, XPS, UV–vis and VSM, respectively. TEM image …