Tuning the Electronic Properties of Main-Group Species by N-Heterocyclic Vinyl (NHV) Scaffolds

RS Ghadwal - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Molecules and materials with easily tunable electronic structures and properties
are at the forefront of contemporary research. π-Conjugation is fundamental in organic …

Electron‐deficient conjugated materials via p–π* conjugation with boron: extending monomers to oligomers, macrocycles, and polymers

X Yin, J Liu, F Jäkle - Chemistry–A European Journal, 2021 - Wiley Online Library
The extension of conjugated organoboranes from monomeric species to oligomers,
macrocycles, and polymers offers access to a plethora of fascinating new materials. The p …

Near-infrared-absorbing B–N lewis pair-functionalized anthracenes: electronic structure tuning, conformational isomerism, and applications in photothermal cancer …

K Liu, Z Jiang, RA Lalancette, X Tang… - Journal of the American …, 2022 - ACS Publications
B–N-fused dianthracenylpyrazine derivatives are synthesized to generate new low gap
chromophores. Photophysical and electrochemical, crystal packing, and theoretical studies …

Optical waveguides in organic crystals of polycyclic arenes

D Tian, Y Chen - Advanced Optical Materials, 2021 - Wiley Online Library
Organic crystals which can confine and guide optical waves on command are currently of
considerable interest because of their tremendous potentials in broadband communications …

Polycyclic aromatic hydrocarbons containing heavy group 14 elements: From synthetic challenges to optoelectronic devices

T Delouche, M Hissler, PA Bouit - Coordination Chemistry Reviews, 2022 - Elsevier
Polycyclic aromatic hydrocarbons (PAHs) are important organic building blocks for
optoelectronic applications. Among the various molecular engineering strategies (π …

Design of organophosphorus materials for organic electronics and bio-applications

E Regulska, C Romero-Nieto - Materials Today Chemistry, 2021 - Elsevier
Abstract π-Extended molecules are key components for the development of materials
science. In fact, polyaromatic structures are fundamental for the scientific and technological …

Linear Extension of Anthracene via B←N Lewis Pair Formation: Effects on Optoelectronic Properties and Singlet O2 Sensitization

M Vanga, A Sahoo, RA Lalancette… - Angewandte Chemie …, 2022 - Wiley Online Library
The functionalization of polycyclic aromatic hydrocarbons (PAHs) via B← N Lewis pair
formation offers an opportunity to judiciously fine‐tune the structural features and …

Solvent‐Vapor‐Induced Reversible Single‐Crystal‐to‐Single‐Crystal Transformation of a Triphosphaazatriangulene‐Based Metal–Organic Framework

S Nakatsuka, Y Watanabe, Y Kamakura… - Angewandte Chemie …, 2020 - Wiley Online Library
Abstract A triphosphaazatriangulene (H3L) was synthesized through an intramolecular triple
phospha‐Friedel–Crafts reaction. The H3L triangulene contains three phosphinate groups …

Phosphorus ylides of cage-opened sulphide [60] fullerene derivatives

Y Hashikawa, N Fujikawa, S Okamoto, Y Murata - Dalton Transactions, 2022 - pubs.rsc.org
The partial structural change in cage-opened C60 derivatives by replacing a carbonyl group
with a sulphide moiety significantly lowers the chemical stability of the corresponding …

Intramolecular Phosphacyclization: Polyaromatic Phosphonium P‐Heterocycles with Wide‐Tuning Optical Properties

A Belyaev, YT Chen, ZY Liu… - … A European Journal, 2019 - Wiley Online Library
Rationally designed cationic phospha‐polyaromatic fluorophores were prepared through
intramolecular cyclization of the tertiary ortho‐(acene) phenylene‐phosphines mediated by …