Chem. Rev. 2010, 110, 4023–4078 4023 10.1021/cr100105a 2010 American Chemical
Society Published on Web 07/14/2010 dates from the 19th century. Since 2000, these …

Formation of stable iron hydrides on more nucleophilic (electron-rich) metal centers than
those found in hydrogenases with CO ligands would inhibit or at least slow down function …

The reaction mechanism for the transition metal free direct hydrogenation of bulky imines
catalyzed by the Lewis acid B (C6F5) 3 is investigated in detail by quantum chemical …

Exploration of new organometallic systems based on polyhedral boron clusters has the
potential to solve challenging chemical problems such as the stabilization of reactive …

Tabulating the structures and characteristic NMR properties of 17 iron complexes, 98
ruthenium complexes and 70 osmium complexes that contain dihydrogen or compressed …

In this Perspective we discuss the ability of transition metal complexes to activate and cleave
the Si–H and B–H bonds of hydrosilanes and hydroboranes (tri-and tetra-coordinated) in an …

Understanding the coordination of σ bonds to metal centers is of fundamental importance
and provides insights useful for developing metal-catalyzed transformations.[1] σ …

Despite their inherent instability, phosphinous acids PR 2 OH have emerged in recent years
as a useful class of P-donor ligands for homogeneous catalysis. The present review article …

In situ oxidation of the GaI compound NacNacGa by either N2O or pyridine oxide results in
the generation of a labile monomeric oxide, NacNacGa (O), which can easily cleave the C …

Addition of the amine–boranes H3B⋅ NH2tBu, H3B⋅ NHMe2 and H3B⋅ NH3 to the cationic
ruthenium fragment [Ru (xantphos)(PPh3)(OH2) H][BArF4](2; xantphos= 4, 5‐bis …