Recent developments in MAS DNP-NMR of materials

AGM Rankin, J Trébosc, F Pourpoint… - Solid State Nuclear …, 2019 - Elsevier
Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …

Hyperpolarized water as universal sensitivity booster in biomolecular NMR

C Hilty, D Kurzbach, L Frydman - Nature protocols, 2022 - nature.com
NMR spectroscopy is the only method to access the structural dynamics of biomolecules at
high (atomistic) resolution in their native solution state. However, this method's low …

Dynamic nuclear polarization solid-state NMR spectroscopy for materials research

IB Moroz, M Leskes - Annual Review of Materials Research, 2022 - annualreviews.org
Solid-state nuclear magnetic resonance (NMR) spectroscopy has increasingly been used for
materials characterization as it enables selective detection of elements of interest, as well as …

Nitrogen Substitutions Aggregation and Clustering in Diamonds as Revealed by High-Field Electron Paramagnetic Resonance

O Nir-Arad, DH Shlomi, N Manukovsky… - Journal of the …, 2023 - ACS Publications
Diamonds have been shown to be an excellent platform for quantum computing and
quantum sensing applications. These applications are enabled by the presence of defects in …

High-field dynamic nuclear polarization

B Corzilius - Annual review of physical chemistry, 2020 - annualreviews.org
Dynamic nuclear polarization (DNP) is one of the most prominent methods of sensitivity
enhancement in nuclear magnetic resonance (NMR). Even though solid-state DNP under …

Hypershifted spin spectroscopy with dynamic nuclear polarization at 1.4 K

Z Pang, K Sheberstov, BA Rodin, J Lumsden… - Science …, 2024 - science.org
Dynamic nuclear polarization (DNP) enhances nuclear magnetic resonance (NMR)
sensitivity by transferring polarization from unpaired electrons to nuclei, but nearby nuclear …

Multi Electron Spin Cluster Enabled Dynamic Nuclear Polarization with Sulfonated BDPA

C Tobar, K Albanese, R Chaklashiya… - The Journal of …, 2023 - ACS Publications
Dynamic nuclear polarization (DNP) can amplify the solid-state nuclear magnetic resonance
(NMR) signal by several orders of magnitude. The mechanism of DNP utilizing α, γ …

Dynamic Nuclear Polarization with Conductive Polymers

Q Stern, G Verhaeghe, T El Daraï… - Angewandte Chemie …, 2024 - Wiley Online Library
The low sensitivity of liquid‐state nuclear magnetic resonance (NMR) can be overcome by
hyperpolarizing nuclear spins by dissolution dynamic nuclear polarization (dDNP). It …

Methyl-driven overhauser dynamic nuclear polarization

FA Perras, DF Flesariu, SA Southern… - The Journal of …, 2022 - ACS Publications
The Overhauser effect is unique among DNP mechanisms in that it requires the modulation
of the electron–nuclear hyperfine interactions. While it dominates DNP in liquids and metals …

Solid-like Dynamic Nuclear Polarization Observed in the Fluid Phase of Lipid Bilayers at 9.4 T

AA Kuzhelev, D Dai, V Denysenkov… - Journal of the American …, 2022 - ACS Publications
Dynamic nuclear polarization (DNP) is a powerful method to enhance NMR sensitivity. Much
progress has been achieved recently to optimize DNP performance at high magnetic fields …