Recent developments in the synthesis of dipyrromethanes. A review

NAM Pereira, TMVD Pinho e Melo - Organic Preparations and …, 2014 - Taylor & Francis
Dipyrromethanes are of wide interest as building blocks in organic synthesis, namely, in the
preparation of porphyrins and porphyrin analogs such as meso-substituted corroles …

Synthesis of 3-trifluoromethylpyrazoles via trifluoromethylation/cyclization of α, β-alkynic hydrazones using a hypervalent iodine reagent

G Ji, X Wang, S Zhang, Y Xu, Y Ye, M Li… - Chemical …, 2014 - pubs.rsc.org
Synthesis of 3-trifluoromethylpyrazoles via trifluoromethylation/cyclization of α,β-alkynic
hydrazones using a hypervalent iodine reagent - Chemical Communications (RSC …

Tailoring porphyrin-based electron accepting materials for organic photovoltaics

J Rawson, AC Stuart, W You… - Journal of the American …, 2014 - ACS Publications
The syntheses, potentiometric responses, optical spectra, electronic structural properties,
and integration into photovoltaic devices are described for ethyne-bridged isoindigo …

Synthesis and linear and nonlinear optical properties of low-melting π-extended porphyrins

D Koszelewski, A Nowak-Król, M Drobizhev… - Journal of Materials …, 2013 - pubs.rsc.org
A large and diverse library of trans-A2B2 and A2BC-porphyrins possessing two arylethynyl
substituents at the meso positions has been efficiently synthesized and tested for their two …

Neutral porphyrin derivative exerts anticancer activity by targeting cellular topoisomerase I (Top1) and promotes apoptotic cell death without stabilizing Top1-DNA …

SK Das, A Ghosh, S Paul Chowdhuri… - Journal of Medicinal …, 2018 - ACS Publications
Camptothecin (CPT) selectively traps topoisomerase 1-DNA cleavable complexes (Top1cc)
to promote anticancer activity. Here, we report the design and synthesis of a new class of …

An Efficient Synthesis of Porphyrins with Different meso Substituents that Avoids Scrambling in Aqueous Media

A Nowak‐Król, R Plamont, G Canard… - … A European Journal, 2015 - Wiley Online Library
We have developed new conditions that afford regioisomerically pure trans‐A2B2‐, A3B‐,
and trans‐AB2C‐porphyrins bearing aryl and arylethynyl substituents. The porphyrins were …

Selective Cycloaddition of Tetracyanoethene (TCNE) and 7,7,8,8‐Tetracyano‐p‐quinodimethane (TCNQ) to Afford meso‐Substituted Phenylethynyl Porphyrins

D Koszelewski, A Nowak‐Król… - Chemistry–An Asian …, 2012 - Wiley Online Library
Abstract π‐Extended TCBD‐porphyrins that contained a 1, 1, 4, 4‐tetracyanobuta‐1, 3‐
diene unit were prepared by a highly efficient [2+ 2] cycloaddition of tetracyanoethene …

Photophysical investigation of neutral and diprotonated free-base bis (arylethynyl) porphyrins

PK Goldberg, TJ Pundsack… - The Journal of Physical …, 2011 - ACS Publications
The photophysical properties for a series of free-base arylethynyl porphyrins and the
corresponding trans-disubstituted tetraphenylporphyrin (H2TPP) derivatives lacking …

Cascade Nucleophilic Attack/Addition Cyclization Reactions to Synthesize Oxazolidin-2-imines via (Z)-2-Bromo-3-phenylprop-2-en-1-ols/3-phenylprop-2-yn-1-ols …

Z Li, L Zhao, Y Zhang, H Yan, X Huang… - The Journal of Organic …, 2022 - ACS Publications
Two concise strategies to synthesize oxazolidin-2-imines by cascade nucleophilic
attack/addition cyclization reactions of (Z)-2-bromo-3-phenylprop-2-en-1-ols/3-phenylprop-2 …

Amplified Two‐Photon Absorption in Trans‐A2B2‐Porphyrins Bearing Nitrophenylethynyl Substituents

A Nowak‐Król, CJ Wilson, M Drobizhev… - …, 2012 - Wiley Online Library
We show that peripheral nitro groups enhance the maximum two‐photon absorption cross‐
section of trans‐A2B2‐porphyrins bearing two phenylethynyl substituents by more than one …