Mechanical properties and peculiarities of molecular crystals

WM Awad, DW Davies, D Kitagawa… - Chemical Society …, 2023 - pubs.rsc.org
In the last century, molecular crystals functioned predominantly as a means for determining
the molecular structures via X-ray diffraction, albeit as the century came to a close the …

Design of collective motions from synthetic molecular switches, rotors, and motors

D Dattler, G Fuks, J Heiser, E Moulin, A Perrot… - Chemical …, 2019 - ACS Publications
Precise control over molecular movement is of fundamental and practical importance in
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …

Light-driven liquid crystalline materials: from photo-induced phase transitions and property modulations to applications

HK Bisoyi, Q Li - Chemical Reviews, 2016 - ACS Publications
Light-driven phenomena both in living systems and nonliving materials have enabled truly
fascinating and incredible dynamic architectures with terrific forms and functions. Recently …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

Reconfigurable photoactuator through synergistic use of photochemical and photothermal effects

M Lahikainen, H Zeng, A Priimagi - Nature communications, 2018 - nature.com
A reconfigurable actuator is a stimuli-responsive structure that can be programmed to adapt
different shapes under identical stimulus. Reconfigurable actuators that function without …

A chaotic self-oscillating sunlight-driven polymer actuator

K Kumar, C Knie, D Bléger, MA Peletier… - Nature …, 2016 - nature.com
Nature provides much inspiration for the design of materials capable of motion upon
exposure to external stimuli, and many examples of such active systems have been created …

Controlling motion at the nanoscale: rise of the molecular machines

JM Abendroth, OS Bushuyev, PS Weiss, CJ Barrett - ACS nano, 2015 - ACS Publications
As our understanding and control of intra-and intermolecular interactions evolve, ever more
complex molecular systems are synthesized and assembled that are capable of performing …

The halogen bond in the design of functional supramolecular materials: recent advances

A Priimagi, G Cavallo, P Metrangolo… - Accounts of chemical …, 2013 - ACS Publications
Halogen bonding is an emerging noncovalent interaction for constructing supramolecular
assemblies. Though similar to the more familiar hydrogen bonding, four primary differences …

Multi-stimuli responsive polymers–the all-in-one talents

P Schattling, FD Jochum, P Theato - Polymer Chemistry, 2014 - pubs.rsc.org
Stimuli-responsive polymers have gained increasing attention, which is attributed to the
manifold applications they can be used for. Several years' intensive research was invested …

Arylazopyrazoles: azoheteroarene photoswitches offering quantitative isomerization and long thermal half-lives

CE Weston, RD Richardson, PR Haycock… - Journal of the …, 2014 - ACS Publications
Arylazopyrazoles, a novel class of five-membered azo photoswitches, offer quantitative
photoswitching and high thermal stability of the Z isomer (half-lives of 10 and∼ 1000 days) …