State of the art in composition, fabrication, characterization, and modeling methods of cement-based thermoelectric materials for low-temperature applications

X Liu, R Jani, E Orisakwe, C Johnston… - … and Sustainable Energy …, 2021 - Elsevier
The worldwide energy crisis and environmental deterioration are probably humanity's
greatest challenges. Thermoelectricity, which allows for the mutual conversion between …

Thermodynamics, kinetics, and mechanics of cesium sorption in cement paste: A multiscale assessment

J Arayro, A Dufresne, T Zhou, K Ioannidou, JF Ulm… - Physical Review …, 2018 - APS
Cesium-137 is a common radioactive byproduct found in nuclear spent fuel. Given its 30
year half life, its interactions with potential storage materials—such as cement paste—is of …

Nanomechanical analysis of Gamma-irradiated cement paste exposed to different humidities

J Němeček, P Trávníček, M Keppert, P Halodová… - … and Building Materials, 2023 - Elsevier
The paper characterizes concurrent effects of gamma-irradiation and presence of water in
Portland cement pastes. An extensive nanomechanical quantification (Young's modulus …

Natural radioactivity of the crust as an important factor of the chemical evolution of the early Earth

BG Ershov - Precambrian Research, 2024 - Elsevier
The long-lived (billions of years) 40 K, 235 U, 238 U, and 232 Th isotopes have a high
energy capacity and represent a potent internal source of energy. Together with the external …

Investigation of mechanisms of radiolytic H2 production in CSH: Influence of water content and radiation induced defects

C Yin, A Dannoux-Papin, J Haas, S Esnouf… - Radiation Physics and …, 2022 - Elsevier
Water radiolysis is a major concern for the conditioning of radioactive waste in cement
materials. Synthetic calcium silicate hydrates (CSH), the main hydrates of concrete, were …

Novel Portland cement matrices incorporating a γ-MnO2/Ag2O hydrogen/tritium getter-structure changes and trapping performance

S Lanier, CA Davy, C Albert-Mercier, O Farcy… - Journal of Nuclear …, 2022 - Elsevier
This study investigates novel Portland cement-based mortars, developed for
hydrogen/tritium trapping and radioactive waste immobilization. They incorporate a γ-MnO …

Original behavior of pore water radiolysis in cement-based materials containing sulfide: Coupling between experiments and simulations

P Bouniol, W Guillot, V Dauvois, W Dridi… - Radiation Physics and …, 2018 - Elsevier
Blended cements with high content of blast furnace slag (CEM III/C) can be used for nuclear
waste conditioning because of their low hydration heat as compared to ordinary Portland …

Influence of calcium to silica ratio on H2 gas production in calcium silicate hydrate

C Yin, A Dannoux-Papin, J Haas, JP Renault - Radiation Physics and …, 2019 - Elsevier
Water radiolysis is of particular concern for the conditioning of radioactive waste with cement
materials. For safety assessment, water radiolysis issued from pore solution and hydrates …

Evidence for pore water composition controlling carbonate morphology in concrete and the further effect of gamma radiation

A Potts, L Leay - Construction and Building Materials, 2021 - Elsevier
Radiation, heat and carbonation can all affect the performance of concrete structures. This
study applies either a 1.5 MGy gamma radiation dose or thermal treatment at 60° C, followed …

Thermoelectric properties of cement composite analogues from first principles calculations

E Orisakwe, C Johnston, R Jani, X Liu… - Materials Research …, 2023 - iopscience.iop.org
Buildings are responsible for a considerable fraction of the energy wasted globally every
year, and as a result, excess carbon emissions. While heat is lost directly in colder months …