Oximes are valuable synthetic building blocks with reactivity modes that enable their use in
diverse methodologies, from cycloadditions to bioconjugation. Their reactivity towards …

The selective functionalization of remote C–H bonds via intramolecular hydrogen atom
transfer (HAT) is transformative for organic synthesis. This radical-mediated strategy …

A radical-mediated strategy for β C–H amination of alcohols has been developed. This
approach employs a radical relay chaperone, which serves as a traceless director that …

The first catalytic strategy to harness imidate radicals has been developed. This approach
enables alkene difunctionalization of allyl alcohols by photocatalytic reduction of their oxime …

Background: The chemists have been interested in light as an energy source to induce
chemical reactions since the beginning of the scientific chemistry. This review summarizes …

The first catalytic strategy to harness imidate radicals for C–H functionalization has been
developed. This iodine-catalyzed approach enables β C–H amination of alcohols by an …

Examines the latest applications of photochemistry to generate important intermediates
Presenting the latest breakthroughs in the field of organic photochemistry, this book offers …

The scope of the lanthanide-mediated, intramolecular amination/cyclization reaction was
determined for the formation of substituted quinolizidines, indolizidines, and pyrrolizidines. A …

NAcyl-3, 4-dihydro-1H-2, 1-benzoxazines (3) undergo a thermal decomposition involving
loss of formaldehyde in a retro-Diels–Alder reaction. The resultant N-acylazaxylylenes (4) …

The cyclization mechanisms and regioselectivities of 4-penteniminyl and benzene-
substituted 4-penteniminyl radicals were investigated systematically by density functional …