Many different models have been published with the aim of describing electrolyte thermodynamics. In this study two successful Equations of State (EoS) are compared. The …
This work discusses the introduction of the concentration dependency of relative permittivity in the context of activity coefficient models at different stages of the derivation of the models …
JP Simonin, O Bernard - Fluid Phase Equilibria, 2023 - Elsevier
In their seminal paper of 1923, Debye and Hückel provided the first appropriate description of the effect of ionic strength on the thermodynamic properties of dilute electrolyte solutions …
In this paper, theoretical considerations on electrolyte thermodynamic models are discussed for single and mixed solvent solutions. A literature review has revealed that for many …
Although Hückel proposed the basic idea of using a concentration dependent dielectric constant, ϵ (c), to compute the activity coefficients of ions in electrolytes in 1925 (Hückel …
A Lewenstam, J Migdalski, R Filipek - Sensors and Actuators B: Chemical, 2025 - Elsevier
This report demonstrates the first-ever electrochemical method for direct measurement of the mean ion-activity coefficient in concentrated solutions of sodium hydroxide (NaOH) mixed …
BF Severin, TD Hayes - Journal of Membrane Science, 2024 - Elsevier
A two-parameter model describes the resistance of a membrane challenged with different salt concentrations on either side of the membrane. This model treats the membrane as a …
P Beaujean - Journal of Molecular Liquids, 2024 - Elsevier
This paper investigates the impact of solute-solvent interactions on the redox potentials of nitroxides, with a focus on ionic interactions caused by the presence of electrolytes found in …