Herein, we disclose cyclic (alkyl)(amino) carbenes (CAACs) to be one‐electron reductants
under the formation of a transient radical cation as indicated by EPR spectroscopy. The …

Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals
results in either dimerisation or H-abstracted products, while the outcome depends on the N …

Herein, we report diamidocarbene (DAC)-based Thiele and Tschitschibabin hydrocarbons,
diradicaloids that contain four carbonyl/amido functional groups. The impact of two different …

Two radical cations of bis-BN-based analogues of Thiele's hydrocarbons were facilely
synthesized, fully characterized, and theoretically investigated. One-electron oxidation leads …

Silylformamidine 1 exists in equilibrium with its carbenic form 1′ due to an easy migration
of the silyl group. The reaction of 1 with variously substituted fluorobenzenes proceeds as an …

Alkenes are known to undergo oxidation to radical cations and dications. The radical cations
are often highly reactive and not stable under air. Herein, we report the synthesis, isolation …

The activation of atmospheric molecular dioxygen (O2) is reported, which occurred across a
C (sp3)–C (sp3) bond of a piperazine derivative without any catalyst at ambient conditions …

Bu çalışmada anyonik diradikal (oid) yapıları üzerine öncelikli olarak heteroatom etkisi
incelenmiştir. Böylece hangi heteroatomun (E= B veya Al)(E'= N veya P) singlet-triplet ve …

Throughout 2021, numerous accounts, frontiers, highlights, novel feature articles,
perspectives, tutorials, mini-reviews, as well as full-reviews have appeared, some of which …