Microenvironment engineering of single/dual‐atom catalysts for electrocatalytic application

Y Gao, B Liu, D Wang - Advanced Materials, 2023 - Wiley Online Library
Single/dual‐metal atoms supported on carbon matrix can be modulated by coordination
structure and neighboring active sites. Precisely designing the geometric and electronic …

Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Supramolecular tuning of supported metal phthalocyanine catalysts for hydrogen peroxide electrosynthesis

BH Lee, H Shin, AS Rasouli, H Choubisa, P Ou… - Nature Catalysis, 2023 - nature.com
Two-electron oxygen reduction offers a route to H2O2 that is potentially cost-effective and
less energy-intensive than the industrial anthraquinone process. However, the catalytic …

Edge‐Site Engineering of Defective Fe–N4 Nanozymes with Boosted Catalase‐Like Performance for Retinal Vasculopathies

R Zhang, B Xue, Y Tao, H Zhao, Z Zhang… - Advanced …, 2022 - Wiley Online Library
Extensive efforts are devoted to refining metal sites for optimizing the catalytic performance
of single‐atom nanozymes (SANzymes), while the contribution of the defect environment of …

Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction

M Lu, M Zhang, J Liu, TY Yu, JN Chang… - Journal of the …, 2022 - ACS Publications
Single clusters have attracted extensive research interest in the field of catalysis. However,
achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work …

Single‐atom catalysis for carbon neutrality

L Wang, D Wang, Y Li - Carbon Energy, 2022 - Wiley Online Library
Currently, more than 86% of global energy consumption is still mainly dependent on
traditional fossil fuels, which causes resource scarcity and even emission of high amounts of …

N B OH Site‐Activated Graphene Quantum Dots for Boosting Electrochemical Hydrogen Peroxide Production

M Fan, Z Wang, K Sun, A Wang, Y Zhao… - Advanced …, 2023 - Wiley Online Library
Carbon materials are considered promising 2/4 e− oxygen reduction reaction (ORR)
electrocatalysts for synthesizing H2O2/H2O via regulating heteroatom dopants and …

Tailoring acidic oxygen reduction selectivity on single-atom catalysts via modification of first and second coordination spheres

C Tang, L Chen, H Li, L Li, Y Jiao… - Journal of the …, 2021 - ACS Publications
Product selectivity in multielectron electrocatalytic reactions is crucial to energy conversion
efficiency and chemical production. However, a present practical drawback is the limited …

Engineering the local atomic environments of indium single‐atom catalysts for efficient electrochemical production of hydrogen peroxide

E Zhang, L Tao, J An, J Zhang, L Meng… - Angewandte …, 2022 - Wiley Online Library
The in‐depth understanding of local atomic environment–property relationships of p‐block
metal single‐atom catalysts toward the 2 e− oxygen reduction reaction (ORR) has rarely …

Co(CN)3 catalysts with well-defined coordination structure for the oxygen reduction reaction

K Sun, J Dong, H Sun, X Wang, J Fang, Z Zhuang… - Nature Catalysis, 2023 - nature.com
Metal-nitrogen-doped carbon (MNC) catalysts are promising platinum group metals
alternatives for fuel cell cathodes; however, their randomly formed, unpredictable …