Spin crossover nanomaterials: from fundamental concepts to devices

G Molnár, S Rat, L Salmon, W Nicolazzi… - Advanced …, 2018 - Wiley Online Library
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …

Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale

V Rubio-Giménez, S Tatay… - Chemical Society …, 2020 - pubs.rsc.org
Materials scientists are currently shifting from purely inorganic, organic and silicon-based
materials towards hybrid organic–inorganic materials to develop increasingly complex and …

Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Vapochromic effect in switchable molecular-based spin crossover compounds

E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …

[HTML][HTML] Spin crossover in discrete polynuclear iron (II) complexes

RW Hogue, S Singh, S Brooker - Chemical Society Reviews, 2018 - pubs.rsc.org
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …

Molecular approach to engineer two-dimensional devices for CMOS and beyond-CMOS applications

Y Zhao, M Gobbi, LE Hueso, P Samorì - Chemical Reviews, 2021 - ACS Publications
Two-dimensional materials (2DMs) have attracted tremendous research interest over the
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …

Bistable Spin‐Crossover Nanoparticles for Molecular Electronics

R Torres‐Cavanillas, M Gavara‐Edo… - Advanced …, 2024 - Wiley Online Library
The field of spin‐crossover complexes is rapidly evolving from the study of the spin transition
phenomenon to its exploitation in molecular electronics. Such spin transition is gradual in a …

When 2D materials meet molecules: opportunities and challenges of hybrid organic/inorganic van der Waals heterostructures

M Gobbi, E Orgiu, P Samorì - Advanced Materials, 2018 - Wiley Online Library
Abstract van der Waals heterostructures, composed of vertically stacked inorganic 2D
materials, represent an ideal platform to demonstrate novel device architectures and to …

Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state

C Lochenie, K Schötz, F Panzer, H Kurz… - Journal of the …, 2018 - ACS Publications
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …