Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Recent Advances in Mn, Fe, Co, and Ni-Catalyzed Organic Reactions

LJ Li, Y He, Y Yang, J Guo, Z Lu, C Wang… - CCS …, 2024 - chinesechemsoc.org
This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Nickel-catalyzed acylzincation of allenes with organozincs and CO

X Wu, C Wang, N Liu, J Qu, Y Chen - Nature Communications, 2023 - nature.com
Transition metal-catalyzed carbonylative reaction with CO gas are among the central task in
organic synthesis, enabling the construction of highly valuable carbonyl compound. Here …

Synthesis of Anthranilic Acid Derivatives through Iron-Catalyzed Ortho Amination of Aromatic Carboxamides with N-Chloroamines

T Matsubara, S Asako, L Ilies… - Journal of the American …, 2014 - ACS Publications
Arenes possessing an 8-quinolinylamide group as a directing group are ortho aminated with
N-chloroamines and N-benzoyloxyamines in the presence of an iron/diphosphine catalyst …

Cobalt-catalyzed enantioselective and chemodivergent addition of cyclopropanols to oxabicyclic alkenes

J Yang, Y Sekiguchi, N Yoshikai - ACS Catalysis, 2019 - ACS Publications
We report herein cobalt-catalyzed enantioselective and chemodivergent reactions between
a cyclopropanol and an oxabicyclic alkene via a cobalt homoenolate, which afford either an …

Copper‐Catalyzed Stereoselective Aminoboration of Bicyclic Alkenes

R Sakae, K Hirano, T Satoh, M Miura - Angewandte Chemie, 2015 - Wiley Online Library
A copper‐catalyzed aminoboration of bicyclic alkenes, including oxa‐and
azabenzonorbornadienes, has been developed. With this method, amine and boron …

π-Extended Rubrenes via Dearomative Annulative π-Extension Reaction

W Matsuoka, KP Kawahara, H Ito… - Journal of the …, 2022 - ACS Publications
Among a large variety of organic semiconducting materials, rubrene (5, 6, 11, 12-
tetraphenyltetracene) represents one of the most prominent molecular entities mainly …

Iron‐Catalyzed Diboration and Carboboration of Alkynes

N Nakagawa, T Hatakeyama… - Chemistry–A European …, 2015 - Wiley Online Library
An iron‐catalyzed diboration reaction of alkynes with bis (pinacolato) diboron (B2pin2) and
external borating agents (MeOB (OR) 2) affords diverse symmetrical or unsymmetrical cis‐1 …

Rh (I)–bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives

CM Filloux, T Rovis - Journal of the American Chemical Society, 2015 - ACS Publications
Asymmetric hydroheteroarylation of alkenes represents a convenient entry to elaborated
heterocyclic motifs. While chiral acids are known to mediate asymmetric addition of electron …