Direct analysis in real time—a critical review on DART-MS

JH Gross - Analytical and bioanalytical chemistry, 2014 - Springer
Direct analysis in real time mass spectrometry (DART-MS) has become an established
technique for rapid mass spectral analysis of a large variety of samples. DART-MS is …

Ambient ionization mass spectrometry: current understanding of mechanistic theory; analytical performance and application areas

DJ Weston - Analyst, 2010 - pubs.rsc.org
Ambient ionization mass spectrometry allows the rapid analysis of samples or objects in
their native state in the open environment with no prior preparation. Over the past six years …

Observation of molecular ions and analysis of nonpolar compounds with the direct analysis in real time ion source

RB Cody - Analytical Chemistry, 2009 - ACS Publications
Positive ions in the direct analysis in real time (DART) ion source are commonly formed by
proton transfer. However, the DART source is similar to atmospheric pressure …

Established and emerging atmospheric pressure surface sampling/ionization techniques for mass spectrometry

GJ Van Berkel, SP Pasilis… - Journal of mass …, 2008 - Wiley Online Library
The number and type of atmospheric pressure techniques suitable for sampling analytes
from surfaces, forming ions from these analytes, and subsequently transporting these ions …

Recent developments in ambient ionization techniques for analytical mass spectrometry

GA Harris, L Nyadong, FM Fernandez - Analyst, 2008 - pubs.rsc.org
Ambient ionization techniques enable the interrogation of a variety of samples in their native
state by mass spectrometry, and are rapidly advancing all fields where screening for the …

Quantitation of chemical warfare agents using the direct analysis in real time (DART) technique

JM Nilles, TR Connell, HD Durst - Analytical chemistry, 2009 - ACS Publications
Direct analysis in real time (DART) is an ion source that permits rapid mass spectrometric
detection of gases, liquids, and solids in open air under ambient conditions. It is a unique …

Explosives detection using direct analysis in real time (DART) mass spectrometry

JM Nilles, TR Connell, ST Stokes… - Propellants …, 2010 - Wiley Online Library
The growing use of explosives by terrorists and criminals creates a need for instrumentation
which can rapidly analyze these energetic compounds, preferably on site. Direct analysis in …

Ionization mechanism of positive-ion direct analysis in real time: a transient microenvironment concept

L Song, SC Gibson, D Bhandari, KD Cook… - Analytical …, 2009 - ACS Publications
A transient microenvironment mechanism (TMEM) is proposed to address matrix effects for
direct analysis in real time (DART). When the DART gas stream is in contact with the sample …

Ionization mechanism of negative ion-direct analysis in real time: a comparative study with negative ion-atmospheric pressure photoionization

L Song, AB Dykstra, H Yao… - Journal of the American …, 2011 - ACS Publications
The ionization mechanism of negative ion-direct analysis in real time (NI-DART) has been
investigated using over 42 compounds, including fullerenes, perfluorocarbons (PFC) …

Characterization of direct-current atmospheric-pressure discharges useful for ambient desorption/ionization mass spectrometry

JT Shelley, JS Wiley, GCY Chan… - Journal of the …, 2011 - ACS Publications
Two relatively new ambient ionization sources, direct analysis in real time (DART) and the
flowing atmospheric-pressure afterglow (FAPA), use direct current, atmospheric-pressure …