Photoredox/Palladium Dual Catalysis for Site-Selective C–H Arylation and Acylation of N-Protected Carbazoles in Visible Light

Rajat, N Jain - The Journal of Organic Chemistry, 2023 - ACS Publications
An unprecedented C-1 selective mono-arylation/acylation of N-protected carbazoles with
aryl diazonium salts/glyoxylic acids has been developed in visible light by dual catalytic …

Photoredox Synthesis of Silicon-Containing Isoindolin-1-ones and Deuterated Analogues Through Hydrosilylation and Deuterium-silylation

GQ Wang, Y Zhang, YX Zhou, D Yang… - The Journal of …, 2024 - ACS Publications
An efficient, practical, and metal-free protocol for the synthesis of silicon-containing
isoindolin-1-ones and deuterated analogues via the synergistic combination of an organic …

Rapid Synthesis of 3-Methyleneisoindolin-1-ones via Metal-Free Tandem Reactions of Ester-Functionalized Aziridines

S Xing, C Jin, P Zhang, J Yang, Y Liang… - The Journal of …, 2024 - ACS Publications
We have disclosed a novel metal-free tandem cyclization reaction for the synthesis of 3-
methyleneisoindolin-1-ones starting from ester-functionalized aziridines. This strategy can …

Photoredox Radical Cascade Cyclization of 2‐Alkynylarylnitriles in Visible Light: Direct Access to 3‐Amino‐1‐indenones

S Rajput, D Garg, N Jain - Advanced Synthesis & Catalysis, 2024 - Wiley Online Library
A photoinduced direct synthesis of 3‐amino‐1‐indenones via radical cascade cyclization
strategy is demonstrated. The methodology involves a domino reaction between 2 …

Metal‐Free and Visible Light‐Induced Difunctionalizations of α‐CF3 Styrenes with Aryl Diazonium Salts and Hetero Nucleophiles

L Zhang, S Liu, M Ma, Y Shen, P Gao… - European Journal of …, 2023 - Wiley Online Library
Metal‐free, visible light‐induced difunctionalizations of α‐CF3 styrenes with aryl diazonium
salts and various hetero nucleophiles (ROH, H2O, N3− and F−) are described. This concise …

Base‐and Visible‐Light‐Promoted Formation of 3‐Benzyl‐3‐Methoxyisoindolin‐1‐one

N Martin, A Moncomble, L Pélinski… - European Journal of …, 2024 - Wiley Online Library
Aryl diazonium salts are versatile compounds known for their reactivity in various
transformations. In this study, we explored the arylation of 3‐methylene isoindolinones using …

Electrochemical Difunctionalization of Alkenes towards the Synthesis of β-Bromoethers under Metal-Free Conditions

Z Fu, F Chen, G Hao, X Yi, J Zeng, H Cai - Synthesis, 2023 - thieme-connect.com
A metal-free electrochemical method for vicinal difunctionalization of various alkenes with
dibromomethane in alcohol as solvent has been well established to synthesize the …

2‐oxo‐2H‐chromen‐7‐olate catalyzed C–C and C–N Bond Formations in Visible Light

V Dixit, S Sharma, N Jain - Asian Journal of Organic Chemistry - Wiley Online Library
7‐hydroxycoumarin is a naturally occurring compound with useful biological and fluorescent
properties. In this work, we demonstrate a base‐assisted photoactivation of 7 …

[引用][C] Photo‐Induced Functionalization of para‐Benzoquinones: Access to Dihydroquinoxalines with a Tetrasubstituted Carbon Stereocenter

V Dixit, A Sharma, A Jangid… - Advanced Synthesis & …, 2023 - Wiley Online Library
Visible light induced activation of para-benzoquinone, and its sequential coupling with
alkynes and ortho-phenylenediamines/ortho-aminophenols is reported. The protocol …