Scandium alloy systems and intermetallics

BY Kotur, E Gratz - Handbook on the Physics and Chemistry of Rare …, 1999 - Elsevier
Publisher Summary The phase diagrams of the Sc–E (E= element) binary systems are
examined in the chapter in the entire or partial concentration region for majority of elements …

Experimental Electron Density of the Complex Carbides Sc3[Fe(C2)2] and Sc3[Co(C2)2]

B Rohrmoser, G Eickerling, M Presnitz… - Journal of the …, 2007 - ACS Publications
The nature of chemical bonding in the complex carbides Sc3 [Fe (C2) 2](1) and Sc3 [Co (C2)
2](2) has been explored by combined experimental and theoretical charge density studies …

Structural variation in novel double salts of silver acetylide with silver nitrate: Fully encapsulated acetylide dianion in different polyhedral silver cages

Guo, GD Zhou, TCW Mak - Journal of the American Chemical …, 1999 - ACS Publications
The reaction of silver acetylide with silver nitrate at 80° C yielded a mixture of the known
compounds Ag2C2⊙ 6AgNO3 (1) and Ag2C2⊙ 5.5 AgNO3⊙ 0.5 H2O (2), which have …

First-principles calculations on the structural, elastic and electronic properties of a class of ternary carbides: A survey investigation

X Xu, Y Bai, P Jin, L Li, X Bai, G Liu, C Tang - Materials & Design, 2017 - Elsevier
First-principles calculations were carried out to investigate the structural, elastic and
electronic properties of a series of ternary carbides with the formula of RTMC 2 (R= Sc, Y, Zr; …

Unprecedented μ4-C26- Anion in Sc4C2@C80

K Tan, X Lu, CR Wang - The Journal of Physical Chemistry B, 2006 - ACS Publications
Metal carbide compound containing highly charged C2 q-(q= 5, 6) moiety is rather scarce.
We show by means of density functional calculations that an unprecedented μ4-C26-anion …

Alloy systems and compounds containing rare earth metals and carbon

V Babizhetskyy, B Kotur, V Levytskyy… - Handbook on the Physics …, 2017 - Elsevier
Data on binary, ternary, and multicomponent systems and compounds containing rare earth
and carbon known through the beginning of 2017 and methods of their synthesis are …

First-principles calculations of ScMC2 (M= Fe, Co, Ni, Cu) ternary carbides: A suitable candidate for shielding purpose

RA Shah, MA Rafiq, MS Akbar, M Haseeb… - Materials Today …, 2024 - Elsevier
Physical properties of scandium-based ternary ScMC 2 (M= Fe, Co, Ni, Cu) carbides have
been investigated using first-principles calculations. The Wien2k code based on Density …

High- and Low-Temperature Modifications of Sc3RuC4 and Sc3OsC4Relativistic Effects, Structure, and Chemical Bonding

C Vogt, RD Hoffmann, UC Rodewald… - Inorganic …, 2009 - ACS Publications
Sc3RuC4 and Sc3OsC4 were synthesized by arc-melting and subsequent annealing. At
room temperature, they crystallize with the Sc3CoC4 structure, space group Immm. At 223 …

First-principles calculations on electronic, mechanical and optical properties of ScMC2 (M= Ti, V, Cr, and Mn) ternary carbides

RA Shah, MA Rafiq, M Haseeb, MN Rasul… - Physica B: Condensed …, 2024 - Elsevier
First-principles calculations have been employed to investigate the physical properties of
scandium-based ternary carbides, denoted as ScMC 2 (M= Ti, V, Cr, Mn). All the studied …

Metal−Metal Bonding in ScTaN2. A New Compound in the System ScN−TaN

R Niewa, DA Zherebtsov, W Schnelle… - Inorganic …, 2004 - ACS Publications
Gray microcrystalline powders of ScTaN2 were prepared from solid-state reactions of δ-ScN
with Ta3N5 powders at T= 1770 K. According to thermal analyses the compound is stable …