Photoelectron spectroscopy in molecular physical chemistry

I Fischer, ST Pratt - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Photoelectron spectroscopy has long been a powerful method in the toolbox of experimental
physical chemistry and molecular physics. Recent improvements in coincidence methods …

Photoelectron Photoion Coincidence Spectroscopy of Biradicals

I Fischer, P Hemberger - ChemPhysChem, 2023 - Wiley Online Library
The electronic structure of biradicals is characterized by the presence of two unpaired
electrons in degenerate or near‐degenerate molecular orbitals. In particular, some of the …

Dimeric Product of Peroxy Radical Self-Reaction Probed with VUV Photoionization Mass Spectrometry and Theoretical Calculations: The Case of C2H5OOC2H5

H Yue, C Zhang, X Lin, Z Wen, W Zhang… - International Journal of …, 2023 - mdpi.com
Organic peroxy radicals (RO2) as key intermediates in tropospheric chemistry exert a
controlling influence on the cycling of atmospheric reactive radicals and the production of …

Combined Modelling of Triply Paired Electronic States of HO2+ ion with 3 Symmetry using Coupled Eigen Model

FGD Xavier - ChemPhysChem, 2023 - Wiley Online Library
The multi state triply paired coupled adiabatic electronic states of, symmetries for the title ion
have been modelled using the triply paired coupled eigen valued functions with the principal …

Structures and properties of known and postulated interstellar cations

L Tinacci, S Pantaleone, A Maranzana… - The Astrophysical …, 2021 - iopscience.iop.org
Positive ions play a fundamental role in interstellar chemistry, especially in cold
environments where chemistry is believed to be mainly ion driven. However, in contrast with …

Cl-Initiated oxidation of methacrolein under NO x-free conditions studied by VUV photoionization mass spectrometry

X Lin, R Hu, Z Ma, H Yue, Z Wen, C Zhang… - Physical Chemistry …, 2022 - pubs.rsc.org
The Cl-initiated oxidation of methacrolein (MACR, C4H6O) under NOx-free conditions has
been investigated in a fast flow tube by using a home-made vacuum ultraviolet (VUV) …

The Boundary between Two Modes of Gas Evolution: Oscillatory (H2 and O2) and Conventional Redox (O2 Only), in the Hydrocarbon/H2O2/Cu(II)/CH3CN …

IY Shchapin, AI Nekhaev - Hydrogen, 2023 - mdpi.com
During the oxidation of hydrocarbons using hydrogen peroxide solutions, the evolution of
gaseous oxygen is a side and undesirable process, in which the consumption of the oxidizer …

Monolayer mono-e bi-metallici di tetra-pyridyl porfirine dall'UHV a pressione quasi-ambiente

F Armillotta - 2023 - arts.units.it
Bi-dimensional metal-organic frameworks (2D-MOF) are a relatively new class of materials
that are gaining particular interest in surface science. Their dimensionality naturally allows …